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SM ISO690:2012 CUZAN, Olesea, SHOVA, Sergiu, MAFFEI, Michel, REGLIER, Marius, BENNISTON, Andrew, TURTA, Constantin. X-ray study and characterization of a new palladium complex with 2-(2h-benzotriazol-2-yl)-4,6-ditert-pentylphenol ligand. In: Physical Methods in Coordination and Supramolecular Chemistry, 8-9 octombrie 2015, Chişinău. Chisinau, Republic of Moldova: 2015, XVIII, p. 152. |
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Physical Methods in Coordination and Supramolecular Chemistry XVIII, 2015 |
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Conferința ""Physical Methods in Coordination and Supramolecular Chemistry"" Chişinău, Moldova, 8-9 octombrie 2015 | ||||||
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Pag. 152-152 | ||||||
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This work reflects the synthesis and characterization of the new bis[2-(2H-benzotriazol-2-yl)-4,6-ditert-pentylphenolato]palladium(II) complex as potential catalyst in the reaction of water splitting. Monocrystals of title compound were obtained upon recrystallization from THF solution. The compound crystallizes in monoclinic P21/n space group, a = 15.7047(8), b = 29.5155(19), c = 20.0274(11) Å, β = 102.241(6) °. Single crystal X-ray diffraction study of the complex reveals two similar but symmetry independent centrosymmetric mononuclear complexes, in which two molecules of bidentate ligand coordinate to the palladium central atom via Nitrogen and two Oxygen atoms resulting in a distorted square plan coordination of the metal.figureFigure 1. Molecular structure of Bis[2-(2H-benzotriazol-2-yl)-4,6-ditert-pentylphenolato]palladium(II) complex. Elemental analysis and spectroscopic methods (IR, 1H NMR and 13C NMR) are in concordance with the X-ray structure. |
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