| Conţinutul numărului revistei |
| Articolul precedent |
| Articolul urmator |
 8 0 |
 SM ISO690:2012SANDU, Ion Gabriel, GULYA, Aurelian, SANDU, Irina Crina Anca, LUCA, Constantin, SANDU, Gabriel. Studii privind sistemul de reacţie Pd2+ - 2,6 diaminotoluen. In: Revista de Chimie, 2005, vol. 56, pp. 805-809. ISSN 0034-7752. |
| EXPORT metadate: Google Scholar Crossref CERIF DataCite Dublin Core |
 Revista de Chimie |
||||||
| Volumul 56 / 2005 / ISSN 0034-7752 | ||||||
|
||||||
| Pag. 805-809 | ||||||
|
||||||
| Rezumat | ||||||
This paper aims to present novel data of reaction system Pd2+ - 2,6 diaminotoluene, which was studied by pH-metric, chemical, thermal, IR and RMN methods, when is confirmed the presence of two addend molecules in the first coordination sphere, as monochlorhidrate (HL+Cl-), among two water molecules. It is therefore formed a nonelectrolytical lemon-yellow complex, little soluble in water and in most organic solvents, with the molecular formula [Pd(LHCl)2(H2O)2], conflrmed by thermal analysis, IR and NMR spectroscopy, having 1st reaction order and the activation energy of 186,5 kJ/mol, for the main thermal process in the temperature range 238,5-310°C. |
||||||
| Cuvinte-cheie activation energy, Diaminotoluene, Monochlorhidrate, Nonelectrolytical complex, Pd, pKa, pKb, Reaction order |
||||||
|
|
|
|
