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 SM ISO690:2012SANDU, Ion Gabriel, GULYA, Aurelian, SANDU, Irina Crina Anca, LUCA, Constantin, SANDU, Gabriel. Studii privind sistemul de reacţie Pd2+ - 2,6 diaminotoluen. In: Revista de Chimie, 2005, vol. 56, pp. 805-809. ISSN 0034-7752. |
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 Revista de Chimie |
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| Volumul 56 / 2005 / ISSN 0034-7752 | ||||||
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| Pag. 805-809 | ||||||
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This paper aims to present novel data of reaction system Pd2+ - 2,6 diaminotoluene, which was studied by pH-metric, chemical, thermal, IR and RMN methods, when is confirmed the presence of two addend molecules in the first coordination sphere, as monochlorhidrate (HL+Cl-), among two water molecules. It is therefore formed a nonelectrolytical lemon-yellow complex, little soluble in water and in most organic solvents, with the molecular formula [Pd(LHCl)2(H2O)2], conflrmed by thermal analysis, IR and NMR spectroscopy, having 1st reaction order and the activation energy of 186,5 kJ/mol, for the main thermal process in the temperature range 238,5-310°C. |
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| Cuvinte-cheie activation energy, Diaminotoluene, Monochlorhidrate, Nonelectrolytical complex, Pd, pKa, pKb, Reaction order |
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DataCite XML Export
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