| Conţinutul numărului revistei |
| Articolul precedent |
| Articolul urmator |
 903 0 |
 SM ISO690:2012CROITOR, Lilia, CHIŞCA, Diana, COROPCEANU, Eduard, VOLODINA, Galina, PETUHOV, Oleg, FONARI, Marina. Solvent-rich layered cobalt(II) 1,4-benzenedicarboxylate based on binuclear {Co2(μ-OH2)(RCOO)2} secondary building unit. In: Journal of Molecular Structure, 2017, nr. 1137, pp. 136-141. ISSN 0022-2860. DOI: https://doi.org/10.1016/j.molstruc.2017.02.018 |
| EXPORT metadate: Google Scholar Crossref CERIF DataCite Dublin Core |
  Journal of Molecular Structure |
||||||
| Numărul 1137 / 2017 / ISSN 0022-2860 | ||||||
|
||||||
| DOI:https://doi.org/10.1016/j.molstruc.2017.02.018 | ||||||
| Pag. 136-141 | ||||||
|
||||||
| Rezumat | ||||||
The reaction of a ditopic ligand, 1,4-benzenedicarboxylic acid (H2bdc) with Co(CH3COO)2·4H2O in solution resulted in a solvent-rich layered coordination polymer with the composition {[Co2(μ2-OH2)(bdc)2(dmf)2(H2O)2]·(dmf)·3(H2O)}n (1) whose crystal structure was determined by single crystal X-ray diffraction. The compound is built on the binuclear {Co2(μ2-OH2)(COO)2} metal clusters, where each Co(II) atom is coordinated by six oxygen atoms in a distorted octahedral arrangement. The crystal lattice of 1 hosts the dmf and water solvent molecules via the OH⋯O hydrogen bonding with coordination network. The easy destruction of the crystals due to the partial solvent loss occurs rapidly in ambient conditions and is confirmed by the TGA data. |
||||||
| Cuvinte-cheie Binuclear secondary building unit, Cobalt(II), IR, thermogravimetric analysis, X-ray |
||||||
|
DataCite XML Export
<?xml version='1.0' encoding='utf-8'?>
<resource xmlns:xsi='http://www.w3.org/2001/XMLSchema-instance' xmlns='http://datacite.org/schema/kernel-3' xsi:schemaLocation='http://datacite.org/schema/kernel-3 http://schema.datacite.org/meta/kernel-3/metadata.xsd'>
<identifier identifierType='DOI'>10.1016/j.molstruc.2017.02.018</identifier>
<creators>
<creator>
<creatorName>Croitor, L.M.</creatorName>
<affiliation>Institutul de Fizică Aplicată al AŞM, Moldova, Republica</affiliation>
</creator>
<creator>
<creatorName>Chişca, D.F.</creatorName>
<affiliation>Institutul de Fizică Aplicată al AŞM, Moldova, Republica</affiliation>
</creator>
<creator>
<creatorName>Coropceanu, E.B.</creatorName>
<affiliation>Institutul de Chimie al AŞM, Moldova, Republica</affiliation>
</creator>
<creator>
<creatorName>Volodina, G.F.</creatorName>
<affiliation>Institutul de Fizică Aplicată al AŞM, Moldova, Republica</affiliation>
</creator>
<creator>
<creatorName>Petuhov, O.M.</creatorName>
<affiliation>Institutul de Chimie al AŞM, Moldova, Republica</affiliation>
</creator>
<creator>
<creatorName>Fonari, M.S.</creatorName>
<affiliation>Institutul de Fizică Aplicată al AŞM, Moldova, Republica</affiliation>
</creator>
</creators>
<titles>
<title xml:lang='en'>Solvent-rich layered cobalt(II) 1,4-benzenedicarboxylate based on binuclear {Co2(μ-OH2)(RCOO)2} secondary building unit</title>
</titles>
<publisher>Instrumentul Bibliometric National</publisher>
<publicationYear>2017</publicationYear>
<relatedIdentifier relatedIdentifierType='ISSN' relationType='IsPartOf'>0022-2860</relatedIdentifier>
<subjects>
<subject>Binuclear secondary building unit</subject>
<subject>Cobalt(II)</subject>
<subject>IR</subject>
<subject>thermogravimetric analysis</subject>
<subject>X-ray</subject>
</subjects>
<dates>
<date dateType='Issued'>2017-06-05</date>
</dates>
<resourceType resourceTypeGeneral='Text'>Journal article</resourceType>
<descriptions>
<description xml:lang='en' descriptionType='Abstract'><p>The reaction of a ditopic ligand, 1,4-benzenedicarboxylic acid (H<sub>2</sub>bdc) with Co(CH<sub>3</sub>COO)<sub>2</sub>·4H<sub>2</sub>O in solution resulted in a solvent-rich layered coordination polymer with the composition {[Co<sub>2</sub>(μ<sub>2</sub>-OH<sub>2</sub>)(bdc)<sub>2</sub>(dmf)<sub>2</sub>(H<sub>2</sub>O)<sub>2</sub>]·(dmf)·3(H<sub>2</sub>O)}<sub>n</sub> (1) whose crystal structure was determined by single crystal X-ray diffraction. The compound is built on the binuclear {Co<sub>2</sub>(μ<sub>2</sub>-OH<sub>2</sub>)(COO)<sub>2</sub>} metal clusters, where each Co(II) atom is coordinated by six oxygen atoms in a distorted octahedral arrangement. The crystal lattice of 1 hosts the dmf and water solvent molecules via the OH⋯O hydrogen bonding with coordination network. The easy destruction of the crystals due to the partial solvent loss occurs rapidly in ambient conditions and is confirmed by the TGA data.</p></description>
</descriptions>
<formats>
<format>uri</format>
</formats>
</resource>|
|
|
