New materials of B2O3–Bi2O3–Me2O3 (Me = Yb, Lu) systems
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ASADOV, M., AHMEDOVA, N.. New materials of B2O3–Bi2O3–Me2O3 (Me = Yb, Lu) systems. In: Moldavian Journal of the Physical Sciences, 2010, nr. 3-4(9), pp. 280-285. ISSN 1810-648X.
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Moldavian Journal of the Physical Sciences
Numărul 3-4(9) / 2010 / ISSN 1810-648X /ISSNe 2537-6365

New materials of B2O3–Bi2O3–Me2O3 (Me = Yb, Lu) systems


Pag. 280-285

Asadov M., Ahmedova N.
 
Institute of Chemical Problems, National Academy of Sciences of Azerbaijan
 
 
Disponibil în IBN: 19 noiembrie 2013


Rezumat

It is shown that the Yb2O3–Bi2O3–B2O3 system gives a new Yb3Bi2B5O15 compound of a hexagonal crystallographic system. Based on the data on the nature of specimens and by means of X-ray study of obtained samples, we determined the boundaries of glass-formation regions in the Yb2O3–Bi2O3–B2O3 system. Homogeneous glasses were obtained in the following cuts: Bi2O3⋅B2O3 − Lu2O3–B2O3 up to 15 mol % Lu2O3; Lu2O3⋅B2O3−Bi2O3 up to 10 mol % Lu2O3; Bi2O3⋅B2O3 − Lu2O3⋅Bi2O3 up to 15 mol % Lu2O3. Eutectic coordinates of LnBO3– B2O3 (Ln = Се, Pr, Pm, Sm, Tb, Er) systems were calculated at first.

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<title xml:lang='en'>New materials of B2O3&ndash;Bi2O3&ndash;Me2O3 (Me = Yb, Lu) systems</title>
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<description xml:lang='en' descriptionType='Abstract'>It is shown that the Yb2O3–Bi2O3–B2O3 system gives a new Yb3Bi2B5O15 compound of 
a hexagonal crystallographic system. Based on the data on the nature of specimens and by 
means of X-ray study of obtained samples, we determined the boundaries of glass-formation 
regions in the Yb2O3–Bi2O3–B2O3 system. Homogeneous glasses were obtained in the following cuts: Bi2O3⋅B2O3 − Lu2O3–B2O3 up to 15 mol % Lu2O3; Lu2O3⋅B2O3−Bi2O3 up to 10 mol 
% Lu2O3; Bi2O3⋅B2O3 − Lu2O3⋅Bi2O3 up to 15 mol % Lu2O3. Eutectic coordinates of LnBO3–
B2O3 (Ln = Се, Pr, Pm, Sm, Tb, Er) systems were calculated at first. 
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