Magneto-optical study of the zero-field splitting in a mononuclear tetrahedrally coordinated Co(II) compound with a mixed ligand surrounding
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OSTROVSKY, Sergei M., TOMKOWICZ, Zbigniew, FORO, Sabine, REEDIJK, Jan, HAASE, Wolfgang. Magneto-optical study of the zero-field splitting in a mononuclear tetrahedrally coordinated Co(II) compound with a mixed ligand surrounding. In: Polyhedron, 2020, nr. 187, p. 0. ISSN 0277-5387. DOI: https://doi.org/10.1016/j.poly.2020.114630
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Polyhedron
Numărul 187 / 2020 / ISSN 0277-5387 /ISSNe 1873-3719

Magneto-optical study of the zero-field splitting in a mononuclear tetrahedrally coordinated Co(II) compound with a mixed ligand surrounding

DOI:https://doi.org/10.1016/j.poly.2020.114630

Pag. 0-0

Ostrovsky Sergei M.1, Tomkowicz Zbigniew2, Foro Sabine3, Reedijk Jan4, Haase Wolfgang3
 
1 Institute of Applied Physics,
2 Jagiellonian University in Krakow,
3 Technical University Darmstadt,
4 Leiden University
 
 
Disponibil în IBN: 23 iunie 2020


Rezumat

The new mononuclear [Co(dbz)Cl2] (dbz = bis(2-benzimidazolyl)ethane) complex has been studied by magnetic measurements and variable-temperature, variable-field magnetic circular dichroism (MCD) spectroscopy, accompanied by theoretical modelling. The values of the zero-field splitting parameters obtained from different experimental techniques are compared with the quantum-chemical calculations.

Cuvinte-cheie
Magnetic anisotropy, Magnetic circular dichroism, Zero-field splitting

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<dc:creator>Ostrovschii, S.M.</dc:creator>
<dc:creator>Tomkowicz, Z.</dc:creator>
<dc:creator>Foro, S.</dc:creator>
<dc:creator>Reedijk, J.</dc:creator>
<dc:creator>Haase, W.</dc:creator>
<dc:date>2020-09-01</dc:date>
<dc:description xml:lang='en'><p>The new mononuclear [Co(dbz)Cl<sub>2</sub>] (dbz = bis(2-benzimidazolyl)ethane) complex has been studied by magnetic measurements and variable-temperature, variable-field magnetic circular dichroism (MCD) spectroscopy, accompanied by theoretical modelling. The values of the zero-field splitting parameters obtained from different experimental techniques are compared with the quantum-chemical calculations.</p></dc:description>
<dc:identifier>10.1016/j.poly.2020.114630</dc:identifier>
<dc:source>Polyhedron  (187) 0-0</dc:source>
<dc:subject>Magnetic anisotropy</dc:subject>
<dc:subject>Magnetic circular dichroism</dc:subject>
<dc:subject>Zero-field splitting</dc:subject>
<dc:title>Magneto-optical study of the zero-field splitting in a mononuclear tetrahedrally coordinated Co(II) compound with a mixed ligand surrounding</dc:title>
<dc:type>info:eu-repo/semantics/article</dc:type>
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