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 SM ISO690:2012BEIRAKHOV, A., ORLOVA, I., ILIIN, E., CHURAKOV, A., MIHAILOV, Yu.. Molybdenum(VI) complex with N-ISOpropylhydroxylamine. In: Physical Methods in Coordination and Supramolecular Chemistry, 24-26 octombrie 2012, Chişinău. Chisinau, Republic of Moldova: 2012, XVII, p. 52. |
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| Physical Methods in Coordination and Supramolecular Chemistry XVII, 2012 |
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Conferința ""Physical Methods in Coordination and Supramolecular Chemistry"" Chişinău, Moldova, 24-26 octombrie 2012 | ||||||
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A molybdenum(VI) coordination compound with N-isopropylhydroxylamine, [MoO2(i-C3H7NHO)2], was synthesized, and its structure was studied. The main bond lengths and angles in the structure of [MoO2(i-C3H7NHO)2] coincide with those found in the structures of known molybdenum(VI) compounds with N-alkylhydroxylamines [1–3]. A peculiarity of this type of complexes is the bidentate chelate coordination of N-substituted hydroxylamine by molybdenum with the formation of a three-membered O,N-chelate ring. An analogous coordination of N-alkylhydroxylamines is characteristic of uranyl aqua complexes with a similar structure [4].figure[MoO2(i-C3H7NHO)2] [UO2{(CH3)2NO}2(Н2О)2] [4] |
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