Molybdenum(VI) complex with N-ISOpropylhydroxylamine

Beirakhov A.; Orlova I.; Iliin E.; Churakov A.; Mihailov Yu.

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2022-09-26 18:23

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BEIRAKHOV, A., ORLOVA, I., ILIIN, E., CHURAKOV, A., MIHAILOV, Yu.. Molybdenum(VI) complex with N-ISOpropylhydroxylamine. In: Physical Methods in Coordination and Supramolecular Chemistry, 24-26 octombrie 2012, Chişinău. Chisinau, Republic of Moldova: 2012, XVII, p. 52.

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Physical Methods in Coordination and Supramolecular Chemistry
XVII, 2012

Conferința ""Physical Methods in Coordination and Supramolecular Chemistry""
Chişinău, Moldova, 24-26 octombrie 2012

Molybdenum(VI) complex with N-ISOpropylhydroxylamine

Pag. 52-52

Beirakhov A., Orlova I., Iliin E., Churakov A., Mihailov Yu.

Kurnakov Institute of General and Inorganic Chemistry of the RAS, Moscow

Disponibil în IBN: 27 mai 2020

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A molybdenum(VI) coordination compound with N-isopropylhydroxylamine, [MoO2(i-C3H7NHO)2], was synthesized, and its structure was studied. The main bond lengths and angles in the structure of [MoO2(i-C3H7NHO)2] coincide with those found in the structures of known molybdenum(VI) compounds with N-alkylhydroxylamines [1–3]. A peculiarity of this type of complexes is the bidentate chelate coordination of N-substituted hydroxylamine by molybdenum with the formation of a three-membered O,N-chelate ring. An analogous coordination of N-alkylhydroxylamines is characteristic of uranyl aqua complexes with a similar structure [4].figure[MoO2(i-C3H7NHO)2] [UO2{(CH3)2NO}2(Н2О)2] [4]

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