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SM ISO690:2012 DANAC, Ramona, PUI, Aurel, KORZHA, I., AMĂRANDI, Roxana Maria, CIOBANU, Catalina Ionica, APOSTU, Mircea Odin, PALAMARCIUC, Oleg. New M(II) (M=Mn, Co, Ni, Cu, Zn, Pd) coordinative compounds with 2-formylpyridine S-methyl-isothiosemicarbazide. In: Journal of Molecular Structure, 2020, nr. 1207, p. 0. ISSN 0022-2860. DOI: https://doi.org/10.1016/j.molstruc.2020.127747 |
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Journal of Molecular Structure | ||||||
Numărul 1207 / 2020 / ISSN 0022-2860 | ||||||
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DOI:https://doi.org/10.1016/j.molstruc.2020.127747 | ||||||
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The synthesis and structure of the new organic proligand 2-formylpyridine S-methyl-isothiosemicarbazone in a bi-protonated form (HL.2HCl) and its coordination compounds with Mn(II) - [Mn(HL)·Cl2], Co(III) - [CoL2]·ClO4, Ni(II) - [Ni(HL)2]·2ClO4, Cu(II) - [Cu(HL)Cl2]·(H2O), Zn(II) - [Zn(HL)2]·2(ClO4)·(H2O) and Pd(II) - [Pd(HL)·Cl]·Cl are reported. According to the X-ray investigation, the ligand has the molecular form of HL in the case of Mn(II), Cu(II), Zn(II) and Pd(II) compounds, and the deprotonated form L− in case of the Co(III) complex. The ligand coordinates to the metal ions via a N,N,N set of donors atoms in case of Zn(II), Cu(II) and Co(III). For Mn(II), the ligand coordinates via N,N donor atoms, whereas in the case of Pd(II) metal ions, the coordination sphere is N,N,S. This latter coordination mode (via S(CH3)) has been previously reported in case of salicylaldehyde S-alkyl-isothiosemicarbazones. |
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Cuvinte-cheie 2-Formylpyridine, 3d elements, coordination compounds, Thiosemicarbazide, X-ray |
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<meta name="citation_title" content="New M(II) (M=Mn, Co, Ni, Cu, Zn, Pd) coordinative compounds with 2-formylpyridine S-methyl-isothiosemicarbazide"> <meta name="citation_author" content="Danac Ramona"> <meta name="citation_author" content="Pui Aurel"> <meta name="citation_author" content="Korzha I."> <meta name="citation_author" content="Amărandi Roxana Maria"> <meta name="citation_author" content="Ciobanu Catalina Ionica"> <meta name="citation_author" content="Apostu Mircea Odin"> <meta name="citation_author" content="Palamarciuc Oleg"> <meta name="citation_publication_date" content="2020/05/05"> <meta name="citation_journal_title" content="Journal of Molecular Structure"> <meta name="citation_issue" content="1207"> <meta name="citation_pdf_url" content="https://www.sciencedirect.com/science/article/abs/pii/S0022286020300715?via%3Dihub">