Conţinutul numărului revistei |
Articolul precedent |
Articolul urmator |
991 0 |
SM ISO690:2012 DANAC, Ramona, PUI, Aurel, KORZHA, I., AMĂRANDI, Roxana Maria, CIOBANU, Catalina Ionica, APOSTU, Mircea Odin, PALAMARCIUC, Oleg. New M(II) (M=Mn, Co, Ni, Cu, Zn, Pd) coordinative compounds with 2-formylpyridine S-methyl-isothiosemicarbazide. In: Journal of Molecular Structure, 2020, nr. 1207, p. 0. ISSN 0022-2860. DOI: https://doi.org/10.1016/j.molstruc.2020.127747 |
EXPORT metadate: Google Scholar Crossref CERIF DataCite Dublin Core |
Journal of Molecular Structure | ||||||
Numărul 1207 / 2020 / ISSN 0022-2860 | ||||||
|
||||||
DOI:https://doi.org/10.1016/j.molstruc.2020.127747 | ||||||
Pag. 0-0 | ||||||
|
||||||
Rezumat | ||||||
The synthesis and structure of the new organic proligand 2-formylpyridine S-methyl-isothiosemicarbazone in a bi-protonated form (HL.2HCl) and its coordination compounds with Mn(II) - [Mn(HL)·Cl2], Co(III) - [CoL2]·ClO4, Ni(II) - [Ni(HL)2]·2ClO4, Cu(II) - [Cu(HL)Cl2]·(H2O), Zn(II) - [Zn(HL)2]·2(ClO4)·(H2O) and Pd(II) - [Pd(HL)·Cl]·Cl are reported. According to the X-ray investigation, the ligand has the molecular form of HL in the case of Mn(II), Cu(II), Zn(II) and Pd(II) compounds, and the deprotonated form L− in case of the Co(III) complex. The ligand coordinates to the metal ions via a N,N,N set of donors atoms in case of Zn(II), Cu(II) and Co(III). For Mn(II), the ligand coordinates via N,N donor atoms, whereas in the case of Pd(II) metal ions, the coordination sphere is N,N,S. This latter coordination mode (via S(CH3)) has been previously reported in case of salicylaldehyde S-alkyl-isothiosemicarbazones. |
||||||
Cuvinte-cheie 2-Formylpyridine, 3d elements, coordination compounds, Thiosemicarbazide, X-ray |
||||||
|
Crossref XML Export
<?xml version='1.0' encoding='utf-8'?> <doi_batch version='4.3.7' xmlns='http://www.crossref.org/schema/4.3.7' xmlns:xsi='http://www.w3.org/2001/XMLSchema-instance' xsi:schemaLocation='http://www.crossref.org/schema/4.3.7 http://www.crossref.org/schema/deposit/crossref4.3.7.xsd'> <head> <doi_batch_id>ibn-95460</doi_batch_id> <timestamp>1714541332</timestamp> <depositor> <depositor_name>Information Society Development Instiute, Republic of Moldova</depositor_name> <email_address>idsi@asm.md</email_address> </depositor> </head> <body> <journal> <journal_metadata> <full_title>Journal of Molecular Structure</full_title> <issn media_type='print'>00222860</issn> </journal_metadata> <journal_issue> <publication_date media_type='print'> <year>2020</year> </publication_date> <issue>1207</issue> </journal_issue> <journal_article publication_type='full_text'><titles> <title>New M(II) (M=Mn, Co, Ni, Cu, Zn, Pd) coordinative compounds with 2-formylpyridine S-methyl-isothiosemicarbazide</title> </titles> <contributors> <person_name sequence='first' contributor_role='author'> <given_name>Ramona</given_name> <surname>Danac</surname> </person_name> <person_name sequence='additional' contributor_role='author'> <given_name>Aurel</given_name> <surname>Pui</surname> </person_name> <person_name sequence='additional' contributor_role='author'> <given_name>Ion</given_name> <surname>Corja</surname> </person_name> <person_name sequence='additional' contributor_role='author'> <given_name>Roxana Maria</given_name> <surname>Amărandi</surname> </person_name> <person_name sequence='additional' contributor_role='author'> <given_name>Catalina Ionica</given_name> <surname>Ciobanu</surname> </person_name> <person_name sequence='additional' contributor_role='author'> <given_name>Mircea Odin</given_name> <surname>Apostu</surname> </person_name> <person_name sequence='additional' contributor_role='author'> <given_name>Oleg</given_name> <surname>Palamarciuc</surname> </person_name> </contributors> <publication_date media_type='print'> <year>2020</year> </publication_date> <pages> <first_page>0</first_page> <last_page>0</last_page> </pages> <doi_data> <doi>10.1016/j.molstruc.2020.127747</doi> <resource>http://www.crossref.org/</resource> </doi_data> </journal_article> </journal> </body> </doi_batch>