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SM ISO690:2012 COVACI (CIOBĂNICĂ), Olga, BOUROSH, Pavlina, BOLOGA, Olga, BULHAK, Ion, LOZAN, Vasile, SHOFRANSKY, Valentin. Synthesis and crystal structure of a new Fe(II) α-dioximate with triazine
. In: Chemistry Journal of Moldova, 2013, nr. 1(8), pp. 78-82. ISSN 1857-1727. |
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Chemistry Journal of Moldova | ||||||
Numărul 1(8) / 2013 / ISSN 1857-1727 /ISSNe 2345-1688 | ||||||
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Pag. 78-82 | ||||||
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The interaction of [Fe(DfgH)2Py2] (where DfgH=monodeprotonated diphenylglyioxime, Py-pyridine) and 1,3,5-triazine (Trz) in chloroform resulted in a new coordination compound with the composition [Fe(DfgH)2(Trz)2]·2CHCl3 (1). The crystal structure of 1, determined by single crystal X-ray diffraction, revealed that
Fe(II) atom is coordinated by four oximic nitrogen atoms of two DfgH and two nitrogen atoms of two Trz ligands resulting in octahedral surrounding. |
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Cuvinte-cheie synthesis, 1, 3, crystal structure, Fe(II)dioximate, 5-triazine |
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