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SM ISO690:2012 COVACI (CIOBĂNICĂ), Olga, BOUROSH, Pavlina, BOLOGA, Olga, BULHAK, Ion, LOZAN, Vasile, SHOFRANSKY, Valentin. Synthesis and crystal structure of a new Fe(II) α-dioximate with triazine
. In: Chemistry Journal of Moldova, 2013, nr. 1(8), pp. 78-82. ISSN 1857-1727. |
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Chemistry Journal of Moldova | |||||
Numărul 1(8) / 2013 / ISSN 1857-1727 /ISSNe 2345-1688 | |||||
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Pag. 78-82 | |||||
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The interaction of [Fe(DfgH)2Py2] (where DfgH=monodeprotonated diphenylglyioxime, Py-pyridine) and 1,3,5-triazine (Trz) in chloroform resulted in a new coordination compound with the composition [Fe(DfgH)2(Trz)2]·2CHCl3 (1). The crystal structure of 1, determined by single crystal X-ray diffraction, revealed that
Fe(II) atom is coordinated by four oximic nitrogen atoms of two DfgH and two nitrogen atoms of two Trz ligands resulting in octahedral surrounding. |
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Cuvinte-cheie synthesis, 1, 3, crystal structure, Fe(II)dioximate, 5-triazine |
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<?xml version='1.0' encoding='utf-8'?> <oai_dc:dc xmlns:dc='http://purl.org/dc/elements/1.1/' xmlns:oai_dc='http://www.openarchives.org/OAI/2.0/oai_dc/' xmlns:xsi='http://www.w3.org/2001/XMLSchema-instance' xsi:schemaLocation='http://www.openarchives.org/OAI/2.0/oai_dc/ http://www.openarchives.org/OAI/2.0/oai_dc.xsd'> <dc:creator>Covaci (Ciobănică), O.A.</dc:creator> <dc:creator>Bouroş, P.N.</dc:creator> <dc:creator>Bologa, O.A.</dc:creator> <dc:creator>Bulhac, I.I.</dc:creator> <dc:creator>Lozan, V.I.</dc:creator> <dc:creator>Şofranschii, V.N.</dc:creator> <dc:date>2013-02-01</dc:date> <dc:description xml:lang='en'>The interaction of [Fe(DfgH)2Py2] (where DfgH=monodeprotonated diphenylglyioxime, Py-pyridine) and 1,3,5-triazine (Trz) in chloroform resulted in a new coordination compound with the composition [Fe(DfgH)2(Trz)2]·2CHCl3 (1). The crystal structure of 1, determined by single crystal X-ray diffraction, revealed that Fe(II) atom is coordinated by four oximic nitrogen atoms of two DfgH and two nitrogen atoms of two Trz ligands resulting in octahedral surrounding.</dc:description> <dc:source>Chemistry Journal of Moldova 8 (1) 78-82</dc:source> <dc:subject>synthesis</dc:subject> <dc:subject>Fe(II)dioximate</dc:subject> <dc:subject>1</dc:subject> <dc:subject>3</dc:subject> <dc:subject>5-triazine</dc:subject> <dc:subject>crystal structure</dc:subject> <dc:title>Synthesis and crystal structure of a new Fe(II) α-dioximate with triazine </dc:title> <dc:type>info:eu-repo/semantics/article</dc:type> </oai_dc:dc>