Conţinutul numărului revistei |
Articolul precedent |
Articolul urmator |
719 0 |
SM ISO690:2012 OKUMUŞ, Esra, OZTURK, Sibel Tokdemir, CHUMAKOV, Yurii, NADJAFOV, Arzu , MAMEDOV, N., MAMMADOV, T., WAKITA, Kazuki, SHIM, Yonggu, MIKAILZADE, Faik A., SEYIDOV, Mir Hasan Yu. Identification of Mn dopant in the structure of TlInS 2 layered semiconductor. In: Materials Research Express, 2019, nr. 5(6), p. 0. ISSN -. DOI: https://doi.org/10.1088/2053-1591/ab063e |
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Materials Research Express | ||||||
Numărul 5(6) / 2019 / ISSN - /ISSNe 2053-1591 | ||||||
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DOI:https://doi.org/10.1088/2053-1591/ab063e | ||||||
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Rezumat | ||||||
The structure of TlInS 2 layered semiconductor doped with 0.3% concentration of Mn impurity has been investigated by using x-ray diffraction (XRD) and Electron Paramagnetic Resonance (EPR) spectroscopy. The experiments were carried out to probe the local environment surrounding the Mn dopants in the crystal structure of TlInS 2 . The interatomic distances between Mn - ions and neighboring atoms and effective valence of Mn - ions were determined. XRD - investigation indicated that the effective valence of Mn ions in TlInS 2 is close to +4. It has been obtained that the EPR spectra of TlInS 2 + 0.3% Mn consist of a broad resonance line stemming from interacting spins and a set of hyperfine structure lines originating from the paramagnetic ions. No EPR signal was observed in undoped TlInS 2 semiconductors. The spectra revealed the incorporation of the paramagnetic Mn - cations with low symmetry site in the structure of host TlInS 2 semiconductor crystal. The spin - Hamiltonian parameters of paramagnetic Mn - centers have been estimated ( and hyperfine splitting constant where z axis is perpendicular to layers). The observation of low field broad resonance lines indicates the magnetic inhomogeneity of the sample. It is assumed that weakly interacting Mn - ions in low symmetry site of host TlInS 2 lead to the formation of spin cluster states, which can be considered as a precursor in preparation of new diluted magnetic semiconductor materials on the base of TlInS 2 . |
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Cuvinte-cheie Electron paramagnetic resonance, hyperfine structure, layered semiconductors, X-ray diffraction |
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