Mathematical models based on thermodynamic equilibrium and kinetics of an ion Exchange process
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SIMINICEANU, Ilie, MARCHITAN, Natalia, DUKA, Gh., MEREUTA, Aliona. Mathematical models based on thermodynamic equilibrium and kinetics of an ion Exchange process. In: Revista de Chimie, 2010, vol. 61, pp. 623-626. ISSN 0034-7752.
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Revista de Chimie
Volumul 61 / 2010 / ISSN 0034-7752

Mathematical models based on thermodynamic equilibrium and kinetics of an ion Exchange process


Pag. 623-626

Siminiceanu Ilie1, Marchitan Natalia2, Duka Gh.2, Mereuta Aliona2
 
1 Gheorghe Asachi Technical University of Iasi,
2 Moldova State University
 
 
Disponibil în IBN: 18 iunie 2024


Rezumat

A new adsorbent has been prepared from Amberlite IRA-67 impregnated with the liquid ion- exchanger Amberlite LA-2 dissolved in n- hexane to recover tartaric acid (TA) from aqueous solution. The experiments done on a batch equipment proved the effectiveness of the new material: the separation degree of TA was100% in a contact time less than 30 minutes for the following values of the 6 main factors: solid/ liquid loading > 1 g/L, T= 294 K, initial pH 2.5, initial TA concentration >1 g/L, particle diameter 0.4-1.2 mm, stirring 200 min-1. The equilibrium qe- ce data were better correlated through the Langmuir model (R2= 0.9962) compared to the Freundlich one (R2= 0.8535). The kinetic curves q- τ have been confronted with 4 kinetic models, and the corresponding kinetic constants have been identified. The Final conclusion was that, under the investigated conditions, the slowest step of the process was the intraparticle diffusion.

Cuvinte-cheie
Dumwald- Wagner, Freundlich, Ho-McKay, Kinetic models, Lagergren, Langmuir, Weber-Morris

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<affiliation>Universitatea de Stat din Moldova, Moldova, Republica</affiliation>
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<title xml:lang='en'>Mathematical models based on thermodynamic equilibrium and kinetics of an ion Exchange process</title>
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<subject>Dumwald- Wagner</subject>
<subject>Freundlich</subject>
<subject>Ho-McKay</subject>
<subject>Kinetic models</subject>
<subject>Lagergren</subject>
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<description xml:lang='en' descriptionType='Abstract'><p>A new adsorbent has been prepared from Amberlite IRA-67 impregnated with the liquid ion- exchanger Amberlite LA-2 dissolved in n- hexane to recover tartaric acid (TA) from aqueous solution. The experiments done on a batch equipment proved the effectiveness of the new material: the separation degree of TA was100% in a contact time less than 30 minutes for the following values of the 6 main factors: solid/ liquid loading &gt; 1 g/L, T= 294 K, initial pH 2.5, initial TA concentration &gt;1 g/L, particle diameter 0.4-1.2 mm, stirring 200 min<sup>-1</sup>. The equilibrium q<sub>e</sub>- c<sub>e</sub>&nbsp;data were better correlated through the Langmuir model (R<sup>2</sup>= 0.9962) compared to the Freundlich one (R<sup>2</sup>= 0.8535). The kinetic curves q- &tau; have been confronted with 4 kinetic models, and the corresponding kinetic constants have been identified. The Final conclusion was that, under the investigated conditions, the slowest step of the process was the intraparticle diffusion.</p></description>
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