Tetradecanuclear lanthanide-vanadium &quot;nanochocolates&quot;: Catalytically-active cationic heteropolyoxovanadium clusters

Šimuneková Mária; Prodius Denis; Meriakre V.; Schwendt Peter; Turta Constantin; Bettinelli Marco; Speghini Adolfo; Lan Yanhua; Anson Christopher E.; Powell Annie Katherine

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ŠIMUNEKOVÁ, Mária, PRODIUS, Denis, MERIAKRE, V., SCHWENDT, Peter, TURTA, Constantin, BETTINELLI, Marco, SPEGHINI, Adolfo, LAN, Yanhua, ANSON, Christopher E., POWELL, Annie Katherine. Tetradecanuclear lanthanide-vanadium "nanochocolates": Catalytically-active cationic heteropolyoxovanadium clusters. In: RSC Advances, 2013, vol. 3, pp. 6299-6304. ISSN 2046-2069. DOI: https://doi.org/10.1039/c3ra40385h

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RSC Advances

Volumul 3 / 2013 / ISSN 2046-2069

Tetradecanuclear lanthanide-vanadium "nanochocolates": Catalytically-active cationic heteropolyoxovanadium clusters

DOI:https://doi.org/10.1039/c3ra40385h

Pag. 6299-6304

Šimuneková Mária¹, Prodius Denis²³, Meriakre V.², Schwendt Peter¹, Turta Constantin³, Bettinelli Marco⁴, Speghini Adolfo⁴, Lan Yanhua², Anson Christopher E.², Powell Annie Katherine²⁵

¹ Comenius University,
² Institute of Inorganic Chemistry, Karlsruhe Institute of Technology,
³ Institute of Chemistry of the Academy of Sciences of Moldova,
⁴ Università di Verona,
⁵ Karlsruhe Institute of Technology, Institute of Nanotechnology

Disponibil în IBN: 21 februarie 2024

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Rezumat

The synthesis, structural characterization, magnetic and catalytic properties of a new class of lanthanide-containing cationic heteropolyoxovanadium clusters with a nanochocolate-like structure are reported. The title compounds were characterized by single-crystal and powder X-ray diffraction, IR and ⁵¹V-NMR spectroscopies and magnetic susceptibility measurements.

Cuvinte-cheie
magnetic susceptibility, Nuclear Magnetic Resonance, Nuclear magnetic resonance spectroscopy, rare earth elements, X ray diffraction

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<dc:creator>Simunekova, M.</dc:creator>
<dc:creator>Prodius, D.N.</dc:creator>
<dc:creator>Mereacre, V.M.</dc:creator>
<dc:creator>Schwendt, P.</dc:creator>
<dc:creator>Turtă, C.I.</dc:creator>
<dc:creator>Bettinelli, M.</dc:creator>
<dc:creator>Speghini, A.</dc:creator>
<dc:creator>Lan, Y.</dc:creator>
<dc:creator>Anson, C.</dc:creator>
<dc:creator>Powell, A.</dc:creator>
<dc:date>2013-05-04</dc:date>
<dc:description xml:lang='en'><p>The synthesis, structural characterization, magnetic and catalytic properties of a new class of lanthanide-containing cationic heteropolyoxovanadium clusters with a nanochocolate-like structure are reported. The title compounds were characterized by single-crystal and powder X-ray diffraction, IR and&nbsp;<sup>51</sup>V-NMR spectroscopies and magnetic susceptibility measurements.&nbsp;</p></dc:description>
<dc:identifier>10.1039/c3ra40385h</dc:identifier>
<dc:source>RSC Advances  () 6299-6304</dc:source>
<dc:subject>magnetic susceptibility</dc:subject>
<dc:subject>Nuclear Magnetic Resonance</dc:subject>
<dc:subject>Nuclear magnetic resonance spectroscopy</dc:subject>
<dc:subject>rare earth elements</dc:subject>
<dc:subject>X ray diffraction</dc:subject>
<dc:title>Tetradecanuclear lanthanide-vanadium &quot;nanochocolates&quot;: Catalytically-active cationic heteropolyoxovanadium clusters</dc:title>
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