Observation of surface phonon mode in porous GaP
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KARAVANSKII, Vladimir, ANASTASSAKIS, Evangelos M., RAPTIS, Yiannis S., SOKOLOV, Viatcheslav, TIGINYANU, Ion, URSACHI, Veaceslav. Observation of surface phonon mode in porous GaP. In: Proceedings of SPIE - The International Society for Optical Engineering, Ed. 1, 4-7 septembrie 1995, Prague. Bellingham: The Society of Photo-Optical Instrumentation Engineers (SPIE), 1996, Vol.2777, pp. 21-26. ISBN 0819421626, 978-081942162-3. ISSN 0277786X. DOI: https://doi.org/10.1117/12.232222
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Proceedings of SPIE - The International Society for Optical Engineering
Vol.2777, 1996
Simpozionul "Advanced Materials for Optics and Optoelectronics"
1, Prague, Cehia, 4-7 septembrie 1995

Observation of surface phonon mode in porous GaP

DOI:https://doi.org/10.1117/12.232222

Pag. 21-26

Karavanskii Vladimir, Anastassakis Evangelos M., Raptis Yiannis S., Sokolov Viatcheslav, Tiginyanu Ion, Ursachi Veaceslav
 
Prokhorov General Physics Institute RAS
 
 
Disponibil în IBN: 2 februarie 2024


Rezumat

Simple preparation technique of nanoporous semiconductors by anodization has opened new ways to form and investigate quantum and surface effects in nanosized objects. It has also allowed technologists to extend the range of possible practical applications of well-known semiconducting materials. The bright visible photoluminescence (PL), in particular, of porous silicon has made this material very promising in the technology of light-emitting devices. The visible PL of nanosized silicon particles is supposed to be connected with a quantum size effect which transforms the indirect gap material into a direct gap one with a simultaneous strong increase of EG. This type of band gap engineering approach may be useful when applied to indirect gap semiconductors, other than Si. Porous GaP is such an example; it was fabricated recently and has exhibited intense green PL and a broadened LO phonon Raman peak. In this communication we present detailed experimental results on Raman scattering (RS) spectra of porous GaP layers obtained by electrochemical anodization of (100) and (111) substrates in hydrofluoric acid solution at different current densities.

Cuvinte-cheie
light emitting diodes, phonons, photoluminescence, porous materials, Raman scattering