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 SM ISO690:2012SIMONOV, Yurii A., REVENKO, M., BOUROSH, Pavlina, BULMAGA, Petru, GDANIEC, Maria. Supramolecular organization of the crystal structure of cis-bis(thiosemicarbazide)palladium(II) ortho-hydrophthalate. In: Crystallography Reports, 2009, vol. 54, pp. 846-851. ISSN 1063-7745. DOI: https://doi.org/10.1134/S1063774509050174 |
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  Crystallography Reports |
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| Volumul 54 / 2009 / ISSN 1063-7745 /ISSNe 1562-689X | ||||||
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| DOI:https://doi.org/10.1134/S1063774509050174 | ||||||
| Pag. 846-851 | ||||||
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This paper reports on the synthesis of a new palladium(II) thiosemicarbazide complex of the composition [Pd(HL)2](HPht) 2 • 4H2O(I) (where HL is N(1)H2-N(2)H-C(3) (=S)-N(4)H2 and HPht - is a monoanion of ortho-phthalic acid) and the results of an investigation of its structure. It has been demonstrated that two organic ligands are bidentately coordinated in the neutral form through a set of N and S donor atoms, which are located in the cis position with respect to the central metal atom. Three independent water molecules are joined by hydrogen bonds into the centrosymmetric associate {H2O}6. In the crystal, thiosemi-carbazide cationic complexes of palladium(II), monophthalate anions, and water molecules are self-organized into a supramolecular system with the formation of a three-dimensional structure based on ionic and hydrogen bonds. |
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| Cuvinte-cheie Cationic complexes, Central metals, Centrosymmetric, Donor atoms, Monoanions, Organic ligands, Phthalic acid, Self-organized, Supramolecular organizations, Supramolecular systems, Thiosemicarbazides, Three-dimensional structure, Water molecule |
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