Conţinutul numărului revistei |
Articolul precedent |
Articolul urmator |
162 0 |
SM ISO690:2012 GORBACHEV, Mikhail. Viscosity of near-boiling nonassociated liquids: Dependence on surface tension, molecular mass and intramolecular conformational transitions. In: Physics and Chemistry of Liquids, 2003, vol. 41, pp. 263-270. ISSN 0031-9104. DOI: https://doi.org/10.1080/0031910031000082057 |
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Physics and Chemistry of Liquids | ||||||
Volumul 41 / 2003 / ISSN 0031-9104 /ISSNe 1029-0451 | ||||||
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DOI:https://doi.org/10.1080/0031910031000082057 | ||||||
Pag. 263-270 | ||||||
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Rezumat | ||||||
The equation proposed for near-boiling nonassociated liquids describes a new functional dependence of their viscosity on such physico-chemical characteristics as surface tension and molecular mass. It is shown that the viscosity of liquids with conformationally flexible molecules can be calculated adequately by taking into account the influence of intramolecular conformational transitions on the number of bimolecular collisions in the liquid phase. |
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Cuvinte-cheie Conformational transitions, Near-boiling liquids, Viscosity |
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