Di- and triheteronuclear Cu-Gd and Cu-Gd-Cu complexes with dissymmetric double bridge
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FELLAH, Fatima Zohra Chiboub, COSTES, Jean-Pierre, DAHAN, Francoise, DUHAYON, Carine, NOVITSKY, Ghenadie, TUCHAGUES, Jean-Pierre M., VENDIER, Laure. Di- and triheteronuclear Cu-Gd and Cu-Gd-Cu complexes with dissymmetric double bridge. In: Inorganic Chemistry, 2008, vol. 47, pp. 6444-6451. ISSN 0020-1669. DOI: https://doi.org/10.1021/ic800599r
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Inorganic Chemistry
Volumul 47 / 2008 / ISSN 0020-1669

Di- and triheteronuclear Cu-Gd and Cu-Gd-Cu complexes with dissymmetric double bridge

DOI:https://doi.org/10.1021/ic800599r

Pag. 6444-6451

Fellah Fatima Zohra Chiboub12, Costes Jean-Pierre1, Dahan Francoise1, Duhayon Carine1, Novitsky Ghenadie3, Tuchagues Jean-Pierre M.1, Vendier Laure1
 
1 Laboratoire de Chimie de Coordination du CNRS, Toulouse,
2 Université Abou Bekr Belkaid-Tlemcen,
3 Institute of Chemistry of the Academy of Sciences of Moldova
 
 
Disponibil în IBN: 25 iulie 2023


Rezumat

The study of the Cu-Gd interaction is simplified by the use of heteronuclear Cu-Gd complexes of low nuclearity, such as dinuclear Cu-Gd or trinuclear Cu-Gd-Cu complexes. In the large majority of cases published until now, this interaction presents the advantage of being ferromagnetic. Among the known examples, the complexes with the largest J values have been prepared with use of symmetric Schiff base compartmental ligands, so that the active cores of the molecules involve two phenoxo bridges between the copper and gadolinium ions. Keeping this remark in mind, we decided to synthesize simple complexes in which two different bridges link the copper and gadolinium ions. The structural determinations of a heterodinuclear Cu-Gd and a trinuclear Cu-Gd-Cu complex confirm the asymmetry of the central cores, involving phenoxo and hydroxo bridges. The magnetic studies evidence again the presence of ferromagnetic interactions. These results corroborate preponderance of the planarity of the Cu-O2-Gd core over the dissymmetry of the bridges.