Thermoelectric properties of bismuth telluride nanowires in the constant relaxation-time approximation
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BEJENARI, Igor, KANTSER, Valeriu. Thermoelectric properties of bismuth telluride nanowires in the constant relaxation-time approximation. In: Physical Review B - Condensed Matter and Materials Physics, 2008, vol. 78, p. 0. ISSN 1098-0121. DOI: https://doi.org/10.1103/PhysRevB.78.115322
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Physical Review B - Condensed Matter and Materials Physics
Volumul 78 / 2008 / ISSN 1098-0121 /ISSNe 1550-235X

Thermoelectric properties of bismuth telluride nanowires in the constant relaxation-time approximation

DOI:https://doi.org/10.1103/PhysRevB.78.115322

Pag. 0-0

Bejenari Igor12, Kantser Valeriu1
 
1 Institute of Electronic Engineering and Industrial Technologies, Academy of Sciences of Moldova,
2 Joint Institute of Nuclear Research
 
 
Disponibil în IBN: 25 iunie 2023


Rezumat

Electronic structure of bismuth telluride nanowires with the growth directions [110] and [015] is studied in the framework of the anisotropic effective-mass method using the parabolic band approximation. The components of the electron and hole effective-mass tensors for six valleys are calculated for both growth directions. For a square nanowire, in the temperature range from 77 to 500 K, the dependence of the Seebeck coefficient S, the thermal κ, and electrical conductivity σ, as well as the figure of merit ZT on the nanowire thickness and on the excess hole concentration pex, are investigated in the constant relaxation-time approximation. The carrier confinement is shown to play essential role for nanowires with cross section less than 30×30 nm2. In contrast to the excess holes (impurities), the confinement decreases both the carrier concentration and the thermal conductivity but increases the maximum value of the Seebeck coefficient. The confinement effect is stronger for the direction [015] than for the direction [110] due to the carrier mass difference for these directions. In the restricted temperature range, the size quantum limit is valid when the P-type nanowire cross section is smaller than 8×10 nm2 (6×7 and 5×5 nm2) at the excess hole concentration pex =2×1018 cm-3 (pex=5×1018 cm-3 and pex =1×1019 cm-3 correspondingly). The carrier confinement increases the maximum value of ZT and shifts it toward high temperatures. For the growth direction [110], the maximum value of the figure of merit for the P -type nanowire is equal to 1.4, 1.6, and 2.8, correspondingly, at temperatures 310, 390, and 480 K and the cross sections 30×30, 15×15, and 7×7 nm2 (pex=5×10 18 cm-3). At room temperature, the figure of merit equals 1.2, 1.3, and 1.7, respectively. 

Cuvinte-cheie
thermal conductivity, thermoelectric, Antisite Defects