| Conţinutul numărului revistei |
| Articolul precedent |
| Articolul urmator |
 324 0 |
 SM ISO690:2012BOTEZAT, Olga, FILIPPOVA, Irina, HAUSER, J, KRAMER, Karl W, DECURTINS, Silvio, LIU, Shi-Xia, BACA, Svetlana. Synthesis, crystal structure, and properties of a 3-oxo-trichromium(III) propionate cluster with pyrazole. In: Journal of Coordination Chemistry, 2016, nr. 1(69), pp. 72-80. ISSN 0095-8972. DOI: https://doi.org/10.1080/00958972.2015.1119272 |
| EXPORT metadate: Google Scholar Crossref CERIF DataCite Dublin Core |
 Journal of Coordination Chemistry |
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| Numărul 1(69) / 2016 / ISSN 0095-8972 /ISSNe 1029-0389 | ||||||
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| DOI:https://doi.org/10.1080/00958972.2015.1119272 | ||||||
| Pag. 72-80 | ||||||
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| Rezumat | ||||||
A new 3-oxo trinuclear chromium(III) propionate cluster, [Cr3(3-O)(O2CCH2CH3)6(pyr)3]NO3·0.25(H2O) (1), has been synthesized by reaction of a 3-oxo trinuclear chromium(III) propionate precursor [Cr3(3-O)(O2CCH2CH3)6(H2O)3]NO3 with a pyrazol ligand (pyr) and characterized by IR spectroscopy, single-crystal X-ray structure determination, and thermal analysis. Magnetic susceptibility and magnetization studies revealed antiferromagnetic exchange interactions within the trinuclear Cr(III) cluster (J = -11.9 cm-1) and determined the electronic ground state (S = 1/2) of the compound. |
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| Cuvinte-cheie carboxylate ligand, chromium(III), cluster compound, magnetic properties |
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