Transformation of antiferromagnetic type of exchange interaction into ferromagnetic one in dimer clusters
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GERU, Ion. Transformation of antiferromagnetic type of exchange interaction into ferromagnetic one in dimer clusters. In: Springer Tracts in Modern Physics, 12 noiembrie 2018, Dusseldorf. Dusseldorf, Germania: Springer Verlag, 2018, Vol. 281, pp. 173-209. ISSN 00813869. DOI: https://doi.org/10.1007/978-3-030-01210-6_6
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Springer Tracts in Modern Physics
Vol. 281, 2018
Sesiunea "Springer Tracts in Modern Physics"
Dusseldorf, Germania, 12 noiembrie 2018

Transformation of antiferromagnetic type of exchange interaction into ferromagnetic one in dimer clusters

DOI:https://doi.org/10.1007/978-3-030-01210-6_6

Pag. 173-209

Geru Ion
 
Institute of Chemistry
 
 
Disponibil în IBN: 16 februarie 2022


Rezumat

We consider coordination compounds of ions with unfilled up 3d- and 4f-shell in a weak or intermediary crystalline field, containing dimer clusters in the case when the distance between clusters is more than the distance between the ions forming the cluster. In this case it is possible to neglect the exchange interaction between electrons of different clusters and the structure of the ground state of separate dimer is determined by the intercluster exchange, spin orbital, magnetic dipole–dipole, and hyperfine interactions. The presence of other dimers in the crystal is possible to take into account if populations of energy levels of system upon interacting dimer clusters are calculated. 

Cuvinte-cheie
valence, Spin, spintronics