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SM ISO690:2012 DANILIUK, Oxana, SUWINSKA, Kinga, LAZAR, Adina, COLEMAN, Anthony. Solid state complexes of p-sulfonatocalix[n]arenes with biomolecules. In: Physical Methods in Coordination and Supramolecular Chemistry, 27 septembrie - 1 octombrie 2006, Chişinău. Chisinau, Republic of Moldova: 2006, XVII, p. 71. ISBN 978-9975-62-066-6. |
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Physical Methods in Coordination and Supramolecular Chemistry XVII, 2006 |
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Conferința "The XV-th International Conference Physical Methods in Coordination and Supramolecular Chemistry : The XVII-th Reading in memory of Acad. A.Ablov" Chişinău, Moldova, 27 septembrie - 1 octombrie 2006 | ||||||
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Pag. 71-71 | ||||||
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Calix[n]arenes are self-assembling systems possessing large cavities and able to trap large molecules in molecular cavity and/or in the crystal lattice. The study of biological and biomedical properties of water-soluble p-sulfonatocalix[n]arenes is receiving growing interest due to their ability to complex various molecules in aqueous phase and to act as direct bio-active molecules. In order to better understand the mechanism of this activity the investigation of calixarene complexation of cationic groups present in biomacromolecules is necessary. The solid-state structures of the complexes of the p-sulfonatocalix[n]arenes with organic amines, both aliphatic and heterocyclic, and drugs, such as chlorhexidine, tetracaine, tamoxifen and piribedil will be presented. The role of hydrogen bonding and non-covalent interactions will be discussed.figureInclusion complexes of p-sulfonatocalixarenes with chlorhexidine and cyclohexanediamine |
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