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![]() PETRENKO, Peter A., CHUMAKOV, Yurii, GRAUR, Vasilii О., SMAGLII, Vadim, TSAPKOV, Victor I., GULYA, Aurelian. The crystal structures of [(2-hydroxybenzylidene)-4-(prop-2-en-1-yl)thiosemicarbazido(2-)]-(2,2’-bipyridine)copper and [(2-hydroxybenzylidene)-4-(prop-2-en-1-yl)thiosemicarbazido(2-)]-(1,10-phenanthroline)copper hydrates. In: Materials Science and Condensed Matter Physics, Ed. 8-th Edition, 12-16 septembrie 2016, Chişinău. Chişinău: Institutul de Fizică Aplicată, 2016, Editia 8, p. 188. ISBN 978-9975-9787-1-2. |
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Materials Science and Condensed Matter Physics Editia 8, 2016 |
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Conferința "International Conference on Materials Science and Condensed Matter Physics" 8-th Edition, Chişinău, Moldova, 12-16 septembrie 2016 | |||||||
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Pag. 188-188 | |||||||
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Previously copper coordination compounds of salicylaldehyde 4-allylthiosemicarbazone (H2L) and its derivatives were synthesized and studied. It was determined that these compounds manifest selective antitumor and antimicrobial activities. Therefore, the study of influence of introduction in the inner sphere of cooper coordination compounds of such bidentate amines as 2,2’-bipyridine (2,2’-Bpy) and 1,10-phenanthroline (1,10-Phen) is of considerable interest. The aim of this work is the synthesis and the determination of structural features of [(2-hydroxybenzylidene)-4-(prop-2-en-1-yl)thiosemicarbazido(2-)]-(2,2’-bipyridine)copper [Cu(2,2’-Bpy)L]·H2O (I) and [(2-hydroxybenzylidene)-4-(prop-2-en-1-yl)-thiosemicarbazido(2-)](1,10-phenanthroline)copper [Cu(1,10-Phen)L]·H2O (II) hydrates. The both studied compounds crystallize in the triclinic space group P-1 with the elementary cell for I: a = 10.5446(4), b = 11.5937(10), c = 16.9620(10) Å, α = 85.502(6)o, β = 86.587(4)o, γ = 88.353(5)o, V = 2063.0(2) Å3 (Fig. 1) and for II: a = 10.3860(6), b = 12.4156(8), c = 16.7644(11) Å, α = 87.922(6)o, β = 86.309(5)o, γ = 89.798(5)o, V = 2155.8(2) Å3 (Fig. 2). In both complexes the coordination polyhedron of the copper atoms can be described as a distorted tetragonal pyramid. |
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<?xml version='1.0' encoding='utf-8'?> <resource xmlns:xsi='http://www.w3.org/2001/XMLSchema-instance' xmlns='http://datacite.org/schema/kernel-3' xsi:schemaLocation='http://datacite.org/schema/kernel-3 http://schema.datacite.org/meta/kernel-3/metadata.xsd'> <creators> <creator> <creatorName>Petrenko, P.A.</creatorName> <affiliation>Institutul de Fizică Aplicată al AŞM, Moldova, Republica</affiliation> </creator> <creator> <creatorName>Ciumacov, I.M.</creatorName> <affiliation>Institutul de Fizică Aplicată al AŞM, Moldova, Republica</affiliation> </creator> <creator> <creatorName>Graur, V.O.</creatorName> <affiliation>Universitatea de Stat din Moldova, Moldova, Republica</affiliation> </creator> <creator> <creatorName>Smaglii, V.A.</creatorName> <affiliation>Universitatea de Stat din Moldova, Moldova, Republica</affiliation> </creator> <creator> <creatorName>Ţapcov, V.I.</creatorName> <affiliation>Universitatea de Stat din Moldova, Moldova, Republica</affiliation> </creator> <creator> <creatorName>Gulea, A.P.</creatorName> <affiliation>Universitatea de Stat din Moldova, Moldova, Republica</affiliation> </creator> </creators> <titles> <title xml:lang='en'>The crystal structures of [(2-hydroxybenzylidene)-4-(prop-2-en-1-yl)thiosemicarbazido(2-)]-(2,2’-bipyridine)copper and [(2-hydroxybenzylidene)-4-(prop-2-en-1-yl)thiosemicarbazido(2-)]-(1,10-phenanthroline)copper hydrates</title> </titles> <publisher>Instrumentul Bibliometric National</publisher> <publicationYear>2016</publicationYear> <relatedIdentifier relatedIdentifierType='ISBN' relationType='IsPartOf'>978-9975-9787-1-2</relatedIdentifier> <dates> <date dateType='Issued'>2016</date> </dates> <resourceType resourceTypeGeneral='Text'>Conference Paper</resourceType> <descriptions> <description xml:lang='en' descriptionType='Abstract'><p>Previously copper coordination compounds of salicylaldehyde 4-allylthiosemicarbazone (H2L) and its derivatives were synthesized and studied. It was determined that these compounds manifest selective antitumor and antimicrobial activities. Therefore, the study of influence of introduction in the inner sphere of cooper coordination compounds of such bidentate amines as 2,2’-bipyridine (2,2’-Bpy) and 1,10-phenanthroline (1,10-Phen) is of considerable interest. The aim of this work is the synthesis and the determination of structural features of [(2-hydroxybenzylidene)-4-(prop-2-en-1-yl)thiosemicarbazido(2-)]-(2,2’-bipyridine)copper [Cu(2,2’-Bpy)L]·H2O (I) and [(2-hydroxybenzylidene)-4-(prop-2-en-1-yl)-thiosemicarbazido(2-)](1,10-phenanthroline)copper [Cu(1,10-Phen)L]·H2O (II) hydrates. The both studied compounds crystallize in the triclinic space group P-1 with the elementary cell for I: a = 10.5446(4), b = 11.5937(10), c = 16.9620(10) Å, α = 85.502(6)<sup>o</sup>, β = 86.587(4)<sup>o</sup>, γ = 88.353(5)<sup>o</sup>, V = 2063.0(2) Å3 (Fig. 1) and for II: a = 10.3860(6), b = 12.4156(8), c = 16.7644(11) Å, α = 87.922(6)<sup>o</sup>, β = 86.309(5)<sup>o</sup>, γ = 89.798(5)<sup>o</sup>, V = 2155.8(2) Å3 (Fig. 2). In both complexes the coordination polyhedron of the copper atoms can be described as a distorted tetragonal pyramid.</p></description> </descriptions> <formats> <format>application/pdf</format> </formats> </resource>