A thiolato-bridged octanuclear copper(i,ii) mixedvalence complex with n,n,s-tridentate ligand

Kotera Takanori; Sugimoto Tsukasa; Mikuriya Masahiro

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2021-05-03 09:46

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KOTERA, Takanori, SUGIMOTO, Tsukasa, MIKURIYA, Masahiro. A thiolato-bridged octanuclear copper(i,ii) mixedvalence complex with n,n,s-tridentate ligand . In: Chemistry Journal of Moldova, 2007, nr. 1(2), pp. 102-107. ISSN 1857-1727.

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Chemistry Journal of Moldova

Numărul 1(2) / 2007 / ISSN 1857-1727 /ISSNe 2345-1688

A thiolato-bridged octanuclear copper(i,ii) mixedvalence complex with n,n,s-tridentate ligand

Pag. 102-107

Kotera Takanori, Sugimoto Tsukasa, Mikuriya Masahiro

Disponibil în IBN: 2 decembrie 2013

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Thiolato-bridged complex [CuI 4 CuII 4(peampt)4 Cl8]·2H2 O (Hpeampt = 1-(2-pyridylethyl)amino) methylpropane-2-thiol) has been synthesized and characterized by the elemental analysis, IR and UV-vis spectroscopies and magnetic susceptibility measurement. The X-ray crystal structure analysis of this complex shows a localized mixed-valence octanuclear cage structure made up of four trigonal-bipyramidal CuIIN2 SCl2, two trigonal CuI S2 Cl, and two tetrahedral CuI S2 Cl2 coordination sites. Temperature dependence of magnetic susceptibility (4.5—300 K) shows that a fairly strong antiferromagnetic interaction is operating between the four CuII ions.

Cuvinte-cheie
thiolato-bridged complexes; mixed-valence complexes; copper complexes; octanuclear complexes

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