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<cfResPublDate>2007-10-03</cfResPublDate>
<cfVol>2</cfVol>
<cfIssue>1</cfIssue>
<cfStartPage>102</cfStartPage>
<cfISSN>1857-1727</cfISSN>
<cfURI>https://ibn.idsi.md/ro/vizualizare_articol/6726</cfURI>
<cfTitle cfLangCode='RO' cfTrans='o'>A thiolato-bridged octanuclear copper(i,ii) mixedvalence complex with n,n,s-tridentate ligand
</cfTitle>
<cfKeyw cfLangCode='RO' cfTrans='o'>thiolato-bridged complexes; mixed-valence complexes; copper complexes; octanuclear complexes</cfKeyw>
<cfAbstr cfLangCode='EN' cfTrans='o'>Thiolato-bridged complex [CuI 4 CuII 4(peampt)4 Cl8]·2H2
O (Hpeampt = 1-(2-pyridylethyl)amino) methylpropane-2-thiol) has been synthesized and characterized by the elemental analysis, IR and UV-vis spectroscopies and magnetic susceptibility measurement. The X-ray crystal structure analysis of this complex shows a localized mixed-valence octanuclear cage structure made up of four trigonal-bipyramidal CuIIN2 SCl2, two trigonal CuI S2 Cl, and two tetrahedral CuI S2 Cl2 coordination sites. Temperature dependence of magnetic susceptibility (4.5—300 K) shows that a fairly strong antiferromagnetic interaction is operating between the four CuII ions.
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<cfFamilyNames>Kotera</cfFamilyNames>
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<cfFirstNames>Tsukasa</cfFirstNames>
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