Electron-phonon coupling effects on Yb3+ spectra in several laser crystals
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LUPEI, Aurelia G., LUPEI, Voicu, PRESURA, C., ENAKI, Viorel, PETRARU, Adrian. Electron-phonon coupling effects on Yb3+ spectra in several laser crystals. In: Journal of Physics Condensed Matter, 1999, vol. 11, pp. 3769-3778. ISSN 0953-8984. DOI: https://doi.org/10.1088/0953-8984/11/18/312
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Journal of Physics Condensed Matter
Volumul 11 / 1999 / ISSN 0953-8984 /ISSNe 1361-648X

Electron-phonon coupling effects on Yb3+ spectra in several laser crystals

DOI:https://doi.org/10.1088/0953-8984/11/18/312

Pag. 3769-3778

Lupei Aurelia G.1, Lupei Voicu1, Presura C.1, Enaki Viorel2, Petraru Adrian1
 
1 Institute of Atomic Physics,
2 Moldova State University
 
 
Disponibil în IBN: 1 martie 2024


Rezumat

The complex absorption spectra of Yb3+ in YAG, LiNbO3 and YLF, three important laser crystals, are analysed in terms of electron-phonon coupling effects. The local symmetry for Yb3+ in these crystals is noncentrosymmetric allowing the coexistence of several electron-phonon coupling mechanisms in the formation of vibronic spectra. The shape of several Yb3+ absorption lines is interpreted in terms of the near resonant electron-phonon coupling theory. The computer modelling, by taking into account more phonons in the resonance region enables the assignment of crystal-field levels of the Yb3+ 2F5/2 multiplet and an estimation of electron-phonon coupling strengths. The phonons involved in the near resonance processes were observed in Raman spectra too. For YAG the modelling with a phonon density with four peaks in the near resonant region is made and it gives a good description of the complex experimental pattern. In the case of Yb3+ in LiNbO3 and YLF the use of polarization data evidences also the symmetry characteristics of the electron-phonon coupling.