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 SM ISO690:2012GORINCHOY, Viorina, TURTA, Constantin, SIMONOV, Yurii A., SHOVA, Sergiu, LIPKOVSKII, Ya, SHOFRANSKY, Valentin. Heteronuclear {Fe-Ba, Fe-Sr} salicylate complexes. Synthesis, structure, and physicochemical properties. In: Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, 2009, vol. 35, pp. 279-285. ISSN -. DOI: https://doi.org/10.1134/S1070328409040083 |
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  Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya |
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| Volumul 35 / 2009 / ISSN - /ISSNe 1070-3284 | ||||||
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| DOI:https://doi.org/10.1134/S1070328409040083 | ||||||
| Pag. 279-285 | ||||||
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The reactions of strontium and barium salicylates with iron nitrate gave heterometallic complexes {[FeSr2(Sal)2(SalH) 2(NO3)(DMA)4]} n (I) and {[FeBa 2(Sal)2(SalH)3(DMA)4(H 2O)]} n (II). The solid compounds are one-dimensional coordination polymers where bridging function is performed by salicylic acid residues and the NO 3 - group (in I). The salicylic acid residues are coordinated in the chelating bridging mode, their denticity ranging from 2 to 5. The IR spectra, magnetic properties, and thermal behavior of the complexes were studied. |
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| Cuvinte-cheie Engineering controlled terms Acids, Barium, Barium compounds, Iron compounds, magnetic properties, Strontium Engineering uncontrolled terms Bridging modes, Denticity, heterometallic complexes, Heteronuclear, IR spectrum, Iron nitrates, One-dimensional coordination polymers, physico-chemical properties, Salicylic acids, Solid compounds, Thermal behaviors Engineering main heading Coordination reactions |
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