Conţinutul numărului revistei |
Articolul precedent |
Articolul urmator |
279 0 |
SM ISO690:2012 ANGHEL, Sergiu, CHUMAKOV, Yurii, KRAVTSOV, Victor, VOLODINA, Galina, MITIOGLU, Anatolie, PŁOCHOCKA, Paulina, SUSHKEVICH, Konstantin, MISHINA, E., KULYUK, Leonid. Site-selective luminescence spectroscopy of bound excitons and local band structure of chlorine intercalated 2H- and 3R-MoS2 polytypes. In: Journal of Luminescence, 2016, vol. 177, pp. 331-336. ISSN 0022-2313. DOI: https://doi.org/10.1016/j.jlumin.2016.05.017 |
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Journal of Luminescence | |
Volumul 177 / 2016 / ISSN 0022-2313 | |
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DOI:https://doi.org/10.1016/j.jlumin.2016.05.017 | |
Pag. 331-336 | |
Rezumat | |
Photoluminescence and X-ray diffraction are used to investigate 2H and 3R polytypes of MoS2 layered crystals intercalated with Cl2 molecules. The spectral structure of the observed bound excitons emission is individual for each polytype, which can be used for unambiguous identification of the 2H and 3R polytypes. The DFT band structure calculations have been done for three molecular layers of 2H-MoS2 and 3R-MoS2 polytypes with and without intercalation of Cl2 molecules. The spectroscopic experimental results confirmed theoretical calculations performed for both cases and it has been demonstrated that halogen intercalation completely changes the local band structure of both 2H- and 3R-MoS2 polytypes. |
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Cuvinte-cheie Bound excitons, Halogen molecules, Luminescence, Molybdenum disulfide, Polytype |
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