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 SM ISO690:2012BEJAN, Dana, BAHRIN, Lucian Gabriel, SHOVA, Sergiu, MARANGOCI, Narcisa Laura, ULKU, Kokcam-Demir, LOZAN, Vasile, JANIAK, Christoph. New microporous lanthanide organic frameworks. synthesis, structure, luminescence, sorption, and catalytic acylation of 2-Naphthol. In: Molecules (Basel, Switzerland), 2020, vol. 25, p. 0. ISSN -. DOI: https://doi.org/10.3390/molecules25133055 |
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  Molecules (Basel, Switzerland) |
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| Volumul 25 / 2020 / ISSN - /ISSNe 1420-3049 | |
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| DOI:https://doi.org/10.3390/molecules25133055 | |
| Pag. 0-0 | |
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New metal-organic frameworks (MOF) with lanthanum(III), cerium(III), neodymium(III), europium(III), gadolinium(III), dysprosium(III), and holmium(III)] and the ligand precursor 1,3,5-tris(4-carboxyphenyl)-2,4,6-trimethylbenzene (H3L) were synthesized under solvothermal conditions. Single crystal x-ray analysis confirmed the formation of three-dimensional frameworks of [LnL(H2O)2]n·xDMF·yH2O for Ln = La, Ce, and Nd. From the nitrogen sorption experiments, the compounds showed permanent porosity with Brunauer-Emmett-Teller (BET) surface areas of about 400 m2/g, and thermal stability up to 500 °C. Further investigations showed that these Ln-MOFs exhibit catalytic activity, paving the way for potential applications within the field of catalysis. |
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| Cuvinte-cheie catalysis, lanthanides, Luminescence, Metal-organic frameworks, sorption |
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Dublin Core Export
<?xml version='1.0' encoding='utf-8'?> <oai_dc:dc xmlns:dc='http://purl.org/dc/elements/1.1/' xmlns:oai_dc='http://www.openarchives.org/OAI/2.0/oai_dc/' xmlns:xsi='http://www.w3.org/2001/XMLSchema-instance' xsi:schemaLocation='http://www.openarchives.org/OAI/2.0/oai_dc/ http://www.openarchives.org/OAI/2.0/oai_dc.xsd'> <dc:creator>Bejan, D.</dc:creator> <dc:creator>Bahrin, L.</dc:creator> <dc:creator>Şova, S.G.</dc:creator> <dc:creator>Marangoci, N.</dc:creator> <dc:creator>Ulku, K.</dc:creator> <dc:creator>Lozan, V.I.</dc:creator> <dc:creator>Janiak, C.</dc:creator> <dc:date>2020-07-01</dc:date> <dc:description xml:lang='en'><p>New metal-organic frameworks (MOF) with lanthanum(III), cerium(III), neodymium(III), europium(III), gadolinium(III), dysprosium(III), and holmium(III)] and the ligand precursor 1,3,5-tris(4-carboxyphenyl)-2,4,6-trimethylbenzene (H3L) were synthesized under solvothermal conditions. Single crystal x-ray analysis confirmed the formation of three-dimensional frameworks of [LnL(H2O)2]n·xDMF·yH2O for Ln = La, Ce, and Nd. From the nitrogen sorption experiments, the compounds showed permanent porosity with Brunauer-Emmett-Teller (BET) surface areas of about 400 m2/g, and thermal stability up to 500 °C. Further investigations showed that these Ln-MOFs exhibit catalytic activity, paving the way for potential applications within the field of catalysis.</p></dc:description> <dc:identifier>10.3390/molecules25133055</dc:identifier> <dc:source>Molecules (Basel, Switzerland) () 0-0</dc:source> <dc:subject>catalysis</dc:subject> <dc:subject>lanthanides</dc:subject> <dc:subject>Luminescence</dc:subject> <dc:subject>Metal-organic frameworks</dc:subject> <dc:subject>sorption</dc:subject> <dc:title>New microporous lanthanide organic frameworks. synthesis, structure, luminescence, sorption, and catalytic acylation of 2-Naphthol</dc:title> <dc:type>info:eu-repo/semantics/article</dc:type> </oai_dc:dc>
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