New microporous lanthanide organic frameworks. synthesis, structure, luminescence, sorption, and catalytic acylation of 2-Naphthol

Bejan Dana; Bahrin Lucian Gabriel; Shova Sergiu; Marangoci Narcisa Laura; Ulku Kokcam-Demir; Lozan Vasile; Janiak Christoph

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2023-04-27 11:49

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BEJAN, Dana, BAHRIN, Lucian Gabriel, SHOVA, Sergiu, MARANGOCI, Narcisa Laura, ULKU, Kokcam-Demir, LOZAN, Vasile, JANIAK, Christoph. New microporous lanthanide organic frameworks. synthesis, structure, luminescence, sorption, and catalytic acylation of 2-Naphthol. In: Molecules (Basel, Switzerland), 2020, vol. 25, p. 0. ISSN -. DOI: https://doi.org/10.3390/molecules25133055

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Molecules (Basel, Switzerland)

Volumul 25 / 2020 / ISSN - /ISSNe 1420-3049

New microporous lanthanide organic frameworks. synthesis, structure, luminescence, sorption, and catalytic acylation of 2-Naphthol

DOI:https://doi.org/10.3390/molecules25133055

Pag. 0-0

Bejan Dana¹, Bahrin Lucian Gabriel¹, Shova Sergiu¹, Marangoci Narcisa Laura¹, Ulku Kokcam-Demir², Lozan Vasile¹³, Janiak Christoph²

¹ “Petru Poni” Institute of Macromolecular Chemistry,
² Institut für Anorganische Chemie und Strukturchemie, Heinrich-Heine Universität Düsseldorf,
³ Institute of Chemistry

Disponibil în IBN: 28 septembrie 2020

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New metal-organic frameworks (MOF) with lanthanum(III), cerium(III), neodymium(III), europium(III), gadolinium(III), dysprosium(III), and holmium(III)] and the ligand precursor 1,3,5-tris(4-carboxyphenyl)-2,4,6-trimethylbenzene (H3L) were synthesized under solvothermal conditions. Single crystal x-ray analysis confirmed the formation of three-dimensional frameworks of [LnL(H2O)2]n·xDMF·yH2O for Ln = La, Ce, and Nd. From the nitrogen sorption experiments, the compounds showed permanent porosity with Brunauer-Emmett-Teller (BET) surface areas of about 400 m2/g, and thermal stability up to 500 °C. Further investigations showed that these Ln-MOFs exhibit catalytic activity, paving the way for potential applications within the field of catalysis.

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catalysis, lanthanides, Luminescence, Metal-organic frameworks, sorption

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