Conţinutul numărului revistei |
Articolul precedent |
Articolul urmator |
619 0 |
SM ISO690:2012 OSTROVSKY, Sergei M., TOMKOWICZ, Zbigniew, FORO, Sabine, REEDIJK, Jan, HAASE, Wolfgang. Magneto-optical study of the zero-field splitting in a mononuclear tetrahedrally coordinated Co(II) compound with a mixed ligand surrounding. In: Polyhedron, 2020, nr. 187, p. 0. ISSN 0277-5387. DOI: https://doi.org/10.1016/j.poly.2020.114630 |
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Polyhedron | ||||||
Numărul 187 / 2020 / ISSN 0277-5387 /ISSNe 1873-3719 | ||||||
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DOI:https://doi.org/10.1016/j.poly.2020.114630 | ||||||
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Rezumat | ||||||
The new mononuclear [Co(dbz)Cl2] (dbz = bis(2-benzimidazolyl)ethane) complex has been studied by magnetic measurements and variable-temperature, variable-field magnetic circular dichroism (MCD) spectroscopy, accompanied by theoretical modelling. The values of the zero-field splitting parameters obtained from different experimental techniques are compared with the quantum-chemical calculations. |
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Cuvinte-cheie Magnetic anisotropy, Magnetic circular dichroism, Zero-field splitting |
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