Magneto-optical study of the zero-field splitting in a mononuclear tetrahedrally coordinated Co(II) compound with a mixed ligand surrounding

Ostrovsky Sergei M.; Tomkowicz Zbigniew; Foro Sabine; Reedijk Jan; Haase Wolfgang

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OSTROVSKY, Sergei M., TOMKOWICZ, Zbigniew, FORO, Sabine, REEDIJK, Jan, HAASE, Wolfgang. Magneto-optical study of the zero-field splitting in a mononuclear tetrahedrally coordinated Co(II) compound with a mixed ligand surrounding. In: Polyhedron, 2020, nr. 187, p. 0. ISSN 0277-5387. DOI: https://doi.org/10.1016/j.poly.2020.114630

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Polyhedron

Numărul 187 / 2020 / ISSN 0277-5387 /ISSNe 1873-3719

Magneto-optical study of the zero-field splitting in a mononuclear tetrahedrally coordinated Co(II) compound with a mixed ligand surrounding

DOI:https://doi.org/10.1016/j.poly.2020.114630

Pag. 0-0

Ostrovsky Sergei M.¹, Tomkowicz Zbigniew², Foro Sabine³, Reedijk Jan⁴, Haase Wolfgang³

¹ Institute of Applied Physics,
² Jagiellonian University in Krakow,
³ Technical University Darmstadt,
⁴ Leiden University

Disponibil în IBN: 23 iunie 2020

Rezumat

The new mononuclear [Co(dbz)Cl₂] (dbz = bis(2-benzimidazolyl)ethane) complex has been studied by magnetic measurements and variable-temperature, variable-field magnetic circular dichroism (MCD) spectroscopy, accompanied by theoretical modelling. The values of the zero-field splitting parameters obtained from different experimental techniques are compared with the quantum-chemical calculations.

Cuvinte-cheie
Magnetic anisotropy, Magnetic circular dichroism, Zero-field splitting

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