Some new Cu(II), Co(II) and Ni(II) complexes containing an ONS donor thiosemicarbazone: synthesis, crystal structures and biological activity

Pakhontsu E.; Julea Felicia; Chumakov Yurii; Petrenko Peter A.; Roshu T.; Gulya Aurelian

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2022-12-08 09:09

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PAKHONTSU, E., JULEA, Felicia, CHUMAKOV, Yurii, PETRENKO, Peter A., ROSHU, T., GULYA, Aurelian. Some new Cu(II), Co(II) and Ni(II) complexes containing an ONS donor thiosemicarbazone: synthesis, crystal structures and biological activity. In: Physical Methods in Coordination and Supramolecular Chemistry, 8-9 octombrie 2015, Chişinău. Chisinau, Republic of Moldova: 2015, XVIII, p. 115.

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Physical Methods in Coordination and Supramolecular Chemistry
XVIII, 2015

Conferința ""Physical Methods in Coordination and Supramolecular Chemistry""
Chişinău, Moldova, 8-9 octombrie 2015

Some new Cu(II), Co(II) and Ni(II) complexes containing an ONS donor thiosemicarbazone: synthesis, crystal structures and biological activity

Pag. 115-115

Pakhontsu E.¹, Julea Felicia², Chumakov Yurii³, Petrenko Peter A.³, Roshu T.⁴, Gulya Aurelian²

¹ University of Medicine and Pharmacy “Carol Davilla”, Bucharest,
² Moldova State University,
³ Institute of Applied Physics,
⁴ University of Bucharest

Disponibil în IBN: 22 aprilie 2020

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The coordination chemistry of thiosemicarbazone complexes involving pyrazolone-ring has excited great interest among chemists in recent years due to their applications in catalysis and their relevance to bio-inorganic systems [1- 4]. Complex combinations of Cu(II), Co(II), and Ni(II) with thiosemicarbazone derivatives of 1-phenyl-3-methyl-4-benzoyl-5-pyrazolone 4-R-thiosemicarbazone (where R= CH3, C6H5, C5H5N) were synthesized. The new obtained compounds were characterized by 1H NMR, 13C NMR, IR, UV-Vis, EPR spectroscopy, elemental analysis, molar electric conductibility and, magnetic susceptibility. In addition, the structures of the ligands and six complexes has been determined by X-ray diffraction method.figureFig.1. Molecular structures for two complexes of Cu(II). The ligands and the newly formed complexes were tested for the effects on HL-60 cell proliferation.

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