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SM ISO690:2012 COROPCEANU, Eduard, RIJA, Andrei, LOZAN, Vasile, BULHAK, Ion, DUKA, Gh., KRAVTSOV, Victor, BOUROSH, Pavlina. Discrete Binuclear Cobalt(III) Bis-dioximates with Wheel-and-Axle Topology as Building Blocks to Afford Porous Supramolecular Metal-Organic Frameworks. In: Crystal Growth and Design, 2016, nr. 2(16), pp. 814-820. ISSN 1528-7483. DOI: https://doi.org/10.1021/acs.cgd.5b01402 |
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Crystal Growth and Design | ||||||
Numărul 2(16) / 2016 / ISSN 1528-7483 | ||||||
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DOI:https://doi.org/10.1021/acs.cgd.5b01402 | ||||||
Pag. 814-820 | ||||||
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Vezi articolul | ||||||
Rezumat | ||||||
Three binuclear and one mononuclear cobalt(III) dioximates with the compositions [Co2(dmgH)4(bpy)Cl2]·1.5dmf (1), [Co2(nioxH)4(bpy)Cl2]·0.5H2O (2), [Co2(dmgH)4(bpe)Cl2]·0.5H2O (3), and [Co(dmgH)2(bpy)Cl]·H2O (4) (where dmgH2 = dimethylglyoxime, nioxH2 = 1,2-cyclohexanedionedioxime, bpy = 4,4′-bipyridine, bpe = 1,2-bis(4-pyridyl)ethane, and dmf = N,N-dimethylformamide) were prepared by replacement of water molecule in Co(III) mononuclear dioximates by bpy and bpe ligands. All compounds were characterized by single-crystal X-ray diffraction and spectroscopic techniques. In all complexes Co(III) atoms have an identical octahedral N5Cl environment formulated by four nitrogen atoms of two mono-deprotonated oxime ligands in a square planar mode, and the nitrogen atom of the bpy/bpe molecules and chloride atom in the axial positions. In 1-3 bpy/bpe exobidentate spacer ligands serve as bridging "rods" and unite two planar cobalt(III) bis-dioximates in binuclear complex with wheel-and-axle topology. The packing of bulky binuclear complexes results in formation of porous structure with hourglass-like channels of diameter ca. 0.6-1.3 nm in the crystal of compound 1 and smaller cavities in 2. The sorption properties for 1 were also measured. The π⋯π stacking interaction between monodentate bpy ligands of mononuclear complexes 4 emulate supramolecular binuclear assembly with wheel-and-axle topology. |
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Cuvinte-cheie atoms, Axles, Bins, carbon dioxide, Chlorine compounds, cobalt, Crystalline materials, ligands, Molecules, Nitrogen, Organometallics, single crystals, Supramolecular chemistry, Topology, wheels, X ray diffraction |
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