Recent studies of (+)-3-carene transformations with the retention of the native framework
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2024-03-18 02:32
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547.2/.9 (1)
Органическая химия (484)
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CURLAT, Serghei. Recent studies of (+)-3-carene transformations with the retention of the native framework. In: Chemistry Journal of Moldova, 2019, nr. 2(14), pp. 32-55. ISSN 1857-1727. DOI: https://doi.org/10.19261/cjm.2019.616
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Chemistry Journal of Moldova
Numărul 2(14) / 2019 / ISSN 1857-1727 /ISSNe 2345-1688

Recent studies of (+)-3-carene transformations with the retention of the native framework

DOI:https://doi.org/10.19261/cjm.2019.616
CZU: 547.2/.9

Pag. 32-55

Curlat Serghei
 
Institute of Chemistry
 
 
Disponibil în IBN: 1 ianuarie 2020


Rezumat

This review presents last decade and some past especially relevant studies in the field of (+)-3-carene synthetic transformations. The paper discusses exclusively the transformations of (+)-3-carene, proceeding with the retention of the native bicyclic carbon skeleton. The data concerning the features of epoxidation and oxidation reactions of (+)-3-carene, the synthesis of sulphurand selenium-containing derivatives and their use in asymmetric synthesis are given. It also describes methods for producing amino derivatives of (+)-3-carene, substituted heterocycles based on it, reactions for the preparation of aziridines, azido-alcohols and azidoamines, as well as chiral phosphites as bidentate ligands.

Cuvinte-cheie
( )-3-carene, epoxidation, sulphide, aminoalcohol, azidoalcohol, aziridine