Given the rapidly developing areas of physical and chemical sciences, the physics and chemistry of a new class of piezoelectric materials on the basis of a hybrid matrix of nano and mikropyezoelektric com posites has arisen. For this goal, we developed the following technologies of hybrid composites and a method of controlling the nanostructure of the polymer phase: (1) the immobilization of nano sized dielectric parti cles in a polymer solution using the energy of the plasma channels of powerful electric discharges in air bounded by dielectrics, (2) the creation of active centers in the composites of clusterization by crystallizing them in terms of the plasma electric discharge in an electronegative gas environment, and (3) the control of the polymer phase of the composite by the spectrum analysis of the thermodepolarized current. A technology of obtaining a matrix of hybrid piezoelectric based nanocomposites and micropezoelectrics is proposed. We propose possible mechanisms for the effects of the immobilization and formation of active origins of cluster ization centers of nanoparticles in the polymer phase of the composite.