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<identifier identifierType='DOI'>10.1134/S1070328417050025</identifier>
<creators>
<creator>
<creatorName>Coropceanu, E.B.</creatorName>
<affiliation>Institutul de Chimie al AŞM, Moldova, Republica</affiliation>
</creator>
<creator>
<creatorName>Croitor, L.M.</creatorName>
<affiliation>Institutul de Fizică Aplicată al AŞM, Moldova, Republica</affiliation>
</creator>
<creator>
<creatorName>Ciloci (Deseatnic), A.A.</creatorName>
<affiliation>Institutul de Microbiologie şi Biotehnologie al AŞM, Moldova, Republica</affiliation>
</creator>
<creator>
<creatorName>Tyurina, Z.P.</creatorName>
<affiliation>Institutul de Microbiologie şi Biotehnologie al AŞM, Moldova, Republica</affiliation>
</creator>
<creator>
<creatorName>Dvornina, E.G.</creatorName>
<affiliation>Institutul de Microbiologie şi Biotehnologie al AŞM, Moldova, Republica</affiliation>
</creator>
<creator>
<creatorName>Codreanu, C.</creatorName>
<affiliation>Universitatea de Stat din Tiraspol, Moldova, Republica</affiliation>
</creator>
<creator>
<creatorName>Fonari, M.S.</creatorName>
<affiliation>Institutul de Fizică Aplicată al AŞM, Moldova, Republica</affiliation>
</creator>
</creators>
<titles>
<title xml:lang='en'>Synthesis and structure of mononuclear zinc complexes with pyridine-2-aldoxime</title>
</titles>
<publisher>Instrumentul Bibliometric National</publisher>
<publicationYear>2017</publicationYear>
<subjects>
<subject>coordination compounds</subject>
<subject>crystal structure</subject>
</subjects>
<dates>
<date dateType='Issued'>2017-05-01</date>
</dates>
<resourceType resourceTypeGeneral='Text'>Journal article</resourceType>
<descriptions>
<description xml:lang='en' descriptionType='Abstract'><p>Three mononuclear different-ligand Zn(II) complexes, [Zn(CH<sub>3</sub>COO)<sub>2</sub>(PaoH)<sub>2</sub>] (I), [Zn(PaoH)<sub>2</sub>(DMSO)<sub>2</sub>][BF<sub>4</sub>]<sub>2</sub> (II), and [Zn(NCS)<sub>2</sub>(PaoH)<sub>2</sub>] (III) (DMSO = dimethylsulfoxide) were prepared by the reaction of zinc acetate and tetrafluoroborate with pyridine-2-aldoxime (PaoH). The composition and structure of the complexes were confirmed by IR spectroscopy and X-ray diffraction. All compounds crystallize in the monoclinic system, compounds I and II have space group P2<sub>1</sub>/n, while compound III has space group C2/c. In all compounds, the Zn coordination polyhedron is a distorted octahedron, which is formed by the N<sub>4</sub>O<sub>2</sub> sets of donor atoms in I and II and by N<sub>6</sub> in III. Complex I in the optimal concentration of 5&ndash;10 mg/L was found to stimulate the biosynthesis of standard (pH 4.7) amylases by the micromycete Aspergillus niger CNMN FD 06.</p></description>
</descriptions>
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<format>uri</format>
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