Variable-range hopping conductivity in La1-xCaxMn1-yFeyO3: Evidence of a complex gap in density of states near the fermi level
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LAIHO, Reino, LISUNOV, Konstantin, LÄHDERANTA, Erkki, PETRENKO, Peter A., SALMINEN, J., SHAKHOV, Mikhail, SAFONTCHIK, M., STAMOV, Vladimir, SHUBNIKOV, M., ZAKHVALINSKII, Vasilii. Variable-range hopping conductivity in La1-xCaxMn1-yFeyO3: Evidence of a complex gap in density of states near the fermi level. In: Journal of Physics Condensed Matter, 2002, vol. 14, pp. 8043-8055. ISSN 0953-8984. DOI: https://doi.org/10.1088/0953-8984/14/34/323
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Journal of Physics Condensed Matter
Volumul 14 / 2002 / ISSN 0953-8984 /ISSNe 1361-648X

Variable-range hopping conductivity in La1-xCaxMn1-yFeyO3: Evidence of a complex gap in density of states near the fermi level

DOI:https://doi.org/10.1088/0953-8984/14/34/323

Pag. 8043-8055

Laiho Reino1, Lisunov Konstantin21, Lähderanta Erkki13, Petrenko Peter A.2, Salminen J.1, Shakhov Mikhail14, Safontchik M.14, Stamov Vladimir21, Shubnikov M.14, Zakhvalinskii Vasilii21
 
1 Wihuri Physical Laboratory, University of Turku,
2 Institute of Applied Physics, Academy of Sciences of Moldova,
3 University of Vaasa,
4 Ioffe Physical-Technical Institute, RAS
 
 
Disponibil în IBN: 4 martie 2024


Rezumat

The resistivity, ρ, of ceramic La1-xCaxMn1-yFeyO3 with x = 0.3 and y = 0.0-0.09 is found to obey, between a temperature Tv ≈ 310-330 K and the ferromagnetic-to-paramagnetic transition temperature, TC = 259-119 K (decreasing with y), the Shklovskii-Efros-type variable-range hopping conductivity law, ρ(T) = ρ0(T) exp[(T0/T)1/2]. This behaviour is governed by generation of a soft Coulomb gap δ ≈ 0.42 eV in the density of localized states and a rigid gap δ(T) ≈ δ(Tv)(T/Tv)1/2 with δ(Tv) ≈ 0.16, 0.13 and 0.12 eV at y = 0.03, 0.07 and 0.09, respectively. Deviations from the square root dependence of δ(T), decreasing when y is increased, are observed as T → TC. The prefactor of the resistivity follows the law ρ0(T) ∼ Tm, where m changes from 9/2 at y = 0 to 5/2 in the investigated samples with y = 0.03, 0.07 and 0.09, which is connected to introduction of an additional fluctuating short-range potential by doping with Fe.

Cuvinte-cheie
Engineering controlled terms Electric conductivity, Electronic density of states, Fermi level, ferromagnetism, Lanthanum compounds, Paramagnetism, Superconducting transition temperature, Thermal effects Engineering uncontrolled terms Coulomb gap Engineering main heading Ceramic materials