The 1:1 adduct of antimony trifluoride with [1.5]dibenzothia-18-crown-6

Fonari Marina; Ganin Eduard; Gelmboldt Vladimir; Lipkowski Janusz; Коtlyar Sergei; Kamalov Gerbert

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FONARI, Marina, GANIN, Eduard, GELMBOLDT, Vladimir, LIPKOWSKI, Janusz, КОTLYAR, Sergei, KAMALOV, Gerbert. The 1:1 adduct of antimony trifluoride with [1.5]dibenzothia-18-crown-6. In: Acta Crystallographica Section E: Structure Reports Online, 2006, vol. 62, pp. 1-5. ISSN 1600-5368. DOI: https://doi.org/10.1107/S1600536806012451

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Acta Crystallographica Section E: Structure Reports Online

Volumul 62 / 2006 / ISSN 1600-5368

The 1:1 adduct of antimony trifluoride with [1.5]dibenzothia-18-crown-6

DOI:https://doi.org/10.1107/S1600536806012451

Pag. 1-5

Fonari Marina¹, Ganin Eduard², Gelmboldt Vladimir³, Lipkowski Janusz⁴, Коtlyar Sergei⁵, Kamalov Gerbert⁵

¹ Institute of Applied Physics, Academy of Sciences of Moldova,
² Odessa State Ecological University,
³ Physicochemical Institute of Environmental Protection and Human, Odessa,
⁴ Institute of Physical Chemistry of the Polish Academy of Sciences, Polonia,
⁵ A.V. Bogatsky Physico-Chemical Institute of the NAS of Ukraine

Disponibil în IBN: 22 februarie 2024

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In the title compound [systematic name: 6,7,9,10,12,13,15,16- octahydrodibenzo[n,q][1,4,7,10,13,16]pentaoxathiacyclooctadecine antimony(III) trifluoride clathrate], (C₂₀H₂₄O₅S)SbF ₃], the components are held together via electrostatic interactions between the antimony lone pair and the collective electron system of the macrocycle. The antimony trifluoride molecule is situated in a perching mode above the macrocyclic cavity, its coordination being completed by three crown ether O atoms at distances in the range 2.737(1)-3.136(1). Neighboring 1:1 adducts are linked into chains via C - H⋯F hydrogen bonds.

Cuvinte-cheie
complex, Cuprous Iodide, 2-Phenylbenzothiazole

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