Low-field magnetic properties as indication of disorder, frustration and cluster formation effects in La1-xCaxMn1-yFeyO3
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Электричество. Магнетизм. Электромагнетизм (409)
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LAIHO, Reino, LISUNOV, Konstantin, LÄHDERANTA, Erkki, SALMINEN, J., ZAKHVALINSKII, Vasilii. Low-field magnetic properties as indication of disorder, frustration and cluster formation effects in La1-xCaxMn1-yFeyO3. In: Journal of Magnetism and Magnetic Materials, 2002, vol. 250, pp. 267-274. ISSN 0304-8853. DOI: https://doi.org/10.1016/S0304-8853(02)00407-9
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Journal of Magnetism and Magnetic Materials
Volumul 250 / 2002 / ISSN 0304-8853

Low-field magnetic properties as indication of disorder, frustration and cluster formation effects in La1-xCaxMn1-yFeyO3

DOI:https://doi.org/10.1016/S0304-8853(02)00407-9
CZU: 537.622.5

Pag. 267-274

Laiho Reino1, Lisunov Konstantin12, Lähderanta Erkki13, Salminen J.1, Zakhvalinskii Vasilii12
 
1 Wihuri Physical Laboratory, University of Turku,
2 Institute of Applied Physics, Academy of Sciences of Moldova,
3 University of Vaasa
 
Proiecte:
 
Disponibil în IBN: 16 februarie 2024


Rezumat

Low-field (B=2-80G) DC magnetic susceptibility, χ, is investigated in ceramic La1-xCaxMn1-yFeyO3 (LCMFO) samples with x=0.3. When y is increased from 0 to 0.1 the ferromagnetic (FM) Curie temperature, TC, decreases from 259 to 107K, indicating growth of disorder by iron doping. A transformation of LCMFO from a weakly frustrated FM phase between y≈0-0.05 to a strongly frustrated mixed, FM and glassy, phase between y≈0.07-0.10 is revealed by measurements of magnetic irreversibility and long-time (up to t=105s) relaxation of thermoremanent magnetization. Critical behavior of χ(T) obeying the scaling law χ-1(T)-χ-1(TC)(T/TC-1)γ≡τγ is observed below τcr∼0.05-0.2 with γ=γ1≈1.4 corresponding to a three-dimensional (3D) Heisenberg spin system. Above τcr, χ(T) can be fitted with the same scaling law as for τ<τcr, but with another value of γ=γ2≈1.7, which characterizes a 3D percolation system. The change of γ upon lowering the temperature can be explained by the formation of percolation clusters from an assembly of hole-rich nanoscale particles of the second FM phase embedded into the host LCMFO matrix at T well above TC. The magnetic moments, radii, and concentration of these particles are determined.

Cuvinte-cheie
Critical exponents, magnetic clusters, Magnetic phase boundaries

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<title xml:lang='en'>Low-field magnetic properties as indication of disorder, frustration and cluster formation effects in La1-xCaxMn1-yFeyO3</title>
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<description xml:lang='en' descriptionType='Abstract'><p>Low-field (B=2-80G) DC magnetic susceptibility, &chi;, is investigated in ceramic La<sub>1-x</sub>Ca<sub>x</sub>Mn<sub>1-y</sub>Fe<sub>y</sub>O<sub>3</sub>&nbsp;(LCMFO) samples with x=0.3. When y is increased from 0 to 0.1 the ferromagnetic (FM) Curie temperature, T<sub>C</sub>, decreases from 259 to 107K, indicating growth of disorder by iron doping. A transformation of LCMFO from a weakly frustrated FM phase between y&asymp;0-0.05 to a strongly frustrated mixed, FM and glassy, phase between y&asymp;0.07-0.10 is revealed by measurements of magnetic irreversibility and long-time (up to t=10<sup>5</sup>s) relaxation of thermoremanent magnetization. Critical behavior of &chi;(T) obeying the scaling law &chi;<sup>-1</sup>(T)-&chi;<sup>-1</sup>(T<sub>C</sub>)(T/T<sub>C</sub>-1)<sup>&gamma;</sup>&equiv;&tau;<sup>&gamma;</sup>&nbsp;is observed below &tau;<sub>cr</sub>&sim;0.05-0.2 with &gamma;=&gamma;<sub>1</sub>&asymp;1.4 corresponding to a three-dimensional (3D) Heisenberg spin system. Above &tau;<sub>cr</sub>, &chi;(T) can be fitted with the same scaling law as for &tau;&lt;&tau;<sub>cr</sub>, but with another value of &gamma;=&gamma;<sub>2</sub>&asymp;1.7, which characterizes a 3D percolation system. The change of &gamma; upon lowering the temperature can be explained by the formation of percolation clusters from an assembly of hole-rich nanoscale particles of the second FM phase embedded into the host LCMFO matrix at T well above T<sub>C</sub>. The magnetic moments, radii, and concentration of these particles are determined.</p></description>
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