Kinetics of the excitonic radiative recombination in WS2:Br2 and MoS2:Cl2 layered crystals
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COLEV, Andrei, GHERMAN, Corneliu, MIROVITSKII, Vadim, KULYUK, Leonid, FORTIN, Emery. Kinetics of the excitonic radiative recombination in WS2:Br2 and MoS2:Cl2 layered crystals. In: Journal of Luminescence, 2009, vol. 129, pp. 1945-1947. ISSN 0022-2313. DOI: https://doi.org/10.1016/j.jlumin.2009.05.022
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Journal of Luminescence
Volumul 129 / 2009 / ISSN 0022-2313

Kinetics of the excitonic radiative recombination in WS2:Br2 and MoS2:Cl2 layered crystals

DOI:https://doi.org/10.1016/j.jlumin.2009.05.022

Pag. 1945-1947

Colev Andrei1, Gherman Corneliu1, Mirovitskii Vadim1, Kulyuk Leonid1, Fortin Emery2
 
1 Institute of Applied Physics, Academy of Sciences of Moldova,
2 University of Ottawa
 
 
Disponibil în IBN: 5 octombrie 2023


Rezumat

Due to their layered structure, 2H layered transition metal dichalcogenide indirect bandgap compounds MoS2, WS2 can be intercalated with foreign atoms and molecules. The 2H-MoS2, 2H-WS2 and 2H-WSe2 crystals intercalated with halogen molecules at low temperatures exhibit a strong luminescence due to the bound excitons recombination. In this work, the results of comparative study of the excitonic luminescence kinetics for 2H-WS2:Br2 and 2H-MoS2:Cl2 single crystals are presented. A simple kinetic model describing the temperature dependencies of the steady-state luminescence intensity and of the radiative decay time is proposed. The lifetimes of the excitonic levels and the activation energy of the excitonic luminescence quenching caused by an extrinsic self-trapping process for both studied compounds were determined. 

Cuvinte-cheie
Bound excitons, intercalation, Layered compounds, Luminescence