Reaction of 5-substituted 2-(3-chloropropanoylamino)benzophenone syn- and anti-oximes with sodium hydroxide
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ANDRONATI, Sergei, SIMONOV, Yurii A., PAVLOVSKY, Victor, KULIKOV , Oleg, GDANEC, M., MAZEPA, Aleksandr. Reaction of 5-substituted 2-(3-chloropropanoylamino)benzophenone syn- and anti-oximes with sodium hydroxide. In: Russian Journal of General Chemistry, 2005, vol. 75, pp. 915-922. ISSN 1070-3632. DOI: https://doi.org/10.1007/s11176-005-0345-4
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Russian Journal of General Chemistry
Volumul 75 / 2005 / ISSN 1070-3632 /ISSNe 1608-3350

Reaction of 5-substituted 2-(3-chloropropanoylamino)benzophenone syn- and anti-oximes with sodium hydroxide

DOI:https://doi.org/10.1007/s11176-005-0345-4

Pag. 915-922

Andronati Sergei1, Simonov Yurii A.2, Pavlovsky Victor2, Kulikov Oleg2, Gdanec M.3, Mazepa Aleksandr3
 
1 Institute of Applied Physics, Academy of Sciences of Moldova,
2 A.V. Bogatsky Physico-Chemical Institute of the NAS of Ukraine,
3 Adam Mickiewicz University in Poznan
 
 
Disponibil în IBN: 21 septembrie 2023


Rezumat

Treatment of syn-oximes of 5-substituted 2-(3-chloropropanoylamino)benzophenones with equimolar amount of sodium hydroxide results in formation of syn-oximes of 5-substituted 2-propenoylamino-benzophenones. The corresponding anti isomers under the same conditions give a mixture of anti-oximes of 5-substituted 2-(propenoylamino)benzophenones and 18-membered 11,22-disubstituted 7,8,18,19-tetrahydrodibenzo[d,m][1,10,2,6,11,15]dioxatetraazacyclooctadecine-6, 17(5H,16H)-diones.