Cobalt(II) and nickel(II) coordination compounds with 4-phenylthiosemicarbazidodiacetic acid dihydrazide: Synthesis and study

Lozan Vasile; Gorbachev Mikhail; Bologa Olga; Gulya Aurelian

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LOZAN, Vasile, GORBACHEV, Mikhail, BOLOGA, Olga, GULYA, Aurelian. Cobalt(II) and nickel(II) coordination compounds with 4-phenylthiosemicarbazidodiacetic acid dihydrazide: Synthesis and study. In: Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, 1998, vol. 24, pp. 480-485. ISSN -.

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Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya

Volumul 24 / 1998 / ISSN - /ISSNe 1070-3284

Cobalt(II) and nickel(II) coordination compounds with 4-phenylthiosemicarbazidodiacetic acid dihydrazide: Synthesis and study

Pag. 480-485

Lozan Vasile, Gorbachev Mikhail, Bologa Olga, Gulya Aurelian

Institute of Chemistry of the Academy of Sciences of Moldova

Disponibil în IBN: 6 septembrie 2023

Rezumat

The coordination compounds of the MLX₂ · nH₂O (M = Co²⁺, Ni²⁺, or Zn²⁺ and X = F^-, Cl^-, Br^-, NO₃^-, or NCS^-) type between cobalt(II), nickel(II), and zinc(II) and 4-phenylthiosemicarbazidodiacetic acid dihydrazide (C₆H₅)NHC(S)NHN(CH₂CONHNH₂) ₂(L) were synthesized. The ¹H and ¹³C NMR spectra of the free and coordinated ligand in dimethyl sulfoxide were examined. The MM2 and CNDO/2 calculations of the geometrical and electronic structures of L were carried out

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