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 SM ISO690:2012CUCOȘ, Andrei, MELNIK, E., SIMONOV, Yurii A., ANDRUH, Marius. A heterotrimetallic chain constructed from binuclear [Cu(II)Mn(II)] nodes and trans-[cr(ncs)4(pyz)2]- spacers. In: Revue Roumaine de Chimie, 2009, vol. 54, pp. 119-125. ISSN 0035-3930. |
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  Revue Roumaine de Chimie |
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| Volumul 54 / 2009 / ISSN 0035-3930 | ||||||
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| Pag. 119-125 | ||||||
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The assembly process between [LCuMn]2+ cations and trans-[Cr(NCS)4(pyz)2]- anions affords a linear heterotrimetallic cationic chain, [{LCuMn(H2O)}{Cr(NCS) 4(pyz)2}]n n+, whose charge is counterbalanced by [Cr(NCS)4(pyz)2]- ions [(H2L = the dissymmetric compartmental Schiff-base proligand resulted from the condensation of 2,6-diformyl-4-methyl-phenol with ethylenediamine and diethylenetriamine; pyz = pyrazine). |
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