Ce3+ dopant segregation in Y3Al5O 12 optical ceramics
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ZHAO, Wei, ANGHEL, Sergiu, MANCINI, Cedric E., AMANS, David, BOULON, Georges, EPICIER, Thierry, SHI, Yun, FENG, Xiqi, PAN, Yubai, CHANI, Valery I., YOSHIKAWA, Akira. Ce3+ dopant segregation in Y3Al5O 12 optical ceramics. In: Optical Materials, 2011, vol. 33, pp. 684-687. ISSN 0925-3467. DOI: https://doi.org/10.1016/j.optmat.2010.10.007
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Optical Materials
Volumul 33 / 2011 / ISSN 0925-3467

Ce3+ dopant segregation in Y3Al5O 12 optical ceramics

DOI:https://doi.org/10.1016/j.optmat.2010.10.007

Pag. 684-687

Zhao Wei12, Anghel Sergiu23, Mancini Cedric E.2, Amans David2, Boulon Georges24, Epicier Thierry2, Shi Yun5, Feng Xiqi5, Pan Yubai5, Chani Valery I.4, Yoshikawa Akira4
 
1 University of Science and Technology of China,
2 Université Lyon,
3 Institute of Applied Physics, Academy of Sciences of Moldova,
4 Tohoku University ,
5 Chinese Academy of Science
 
 
Disponibil în IBN: 30 august 2023


Rezumat

Ce3+-doped YAG garnet optical ceramic have been sintered at the Shanghai Institute of Ceramics in China to characterize dopant distribution in optical ceramics by combining optical spectroscopy and two spatially resolved techniques as imaging confocal microscopy and transmission electron microscopy. A strong Ce3+ segregation and spatial variations of content between grains and grain boundaries has been confirmed by quantitative data obtained by TEM microscopy. This observation is another evidence of the inhomogeneous Ce3+ distribution across grain and grain boundaries in optical ceramics comparable to that of Nd3+ ions in YAG ceramics. These results correlate well with low segregation coefficients of Nd3+ and Ce3+ observed in the garnet crystals grown from the melt and/or flux. 

Cuvinte-cheie
Cerium, Optical ceramics, Scintillators, segregation, YAG