Low-dimensional organic crystal tetrathiotetracene-lodide as thermoelectric material: Reality and prospects
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KASIYAN, Anatolie, STOCKHOLM, John G., DUSHCHAC, Viorel, NICIC, Veaceslav. Low-dimensional organic crystal tetrathiotetracene-lodide as thermoelectric material: Reality and prospects. In: Journal of Nanoelectronics and Optoelectronics, 2009, vol. 4, pp. 95-100. ISSN 1555-130X. DOI: https://doi.org/10.1166/jno.2009.1008
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Journal of Nanoelectronics and Optoelectronics
Volumul 4 / 2009 / ISSN 1555-130X

Low-dimensional organic crystal tetrathiotetracene-lodide as thermoelectric material: Reality and prospects

DOI:https://doi.org/10.1166/jno.2009.1008
CZU: 538.9+539.2

Pag. 95-100

Kasiyan Anatolie1, Stockholm John G.2, Dushchac Viorel1, Nicic Veaceslav1
 
1 Technical University of Moldova,
2 Marvel Thermoelectrics
 
 
Disponibil în IBN: 24 august 2023


Rezumat

It is explained the strong dependence of electrical conductivity and very weak dependence of thermopower on crystal purity observed experimentally in ordinary quasi-one-dimensional organic crystals of tetrathiotetracene-iodide, TTT2I3. It is shown theoretically that in really existing crystals TTT2I3 it is possibly to increase the dimensionless thermoelectric figure of merit ZT up to 1.4 at room temperature, if the carriers concentration is diminished by approximately 2.5 times with respect to the concentration in stoichiometric crystals. For purer crystals with a slightly less impurity concentration values of ZT∼ 2 are expected. Whole predicted increase of ZT is expected as a result of the thermoelectric power factor growth.

Cuvinte-cheie
Quasi-one-dimensional Organic Crystal, Tetrathiotetracene-lodide, thermoelectric figure of merit