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![]() OSTROVSKY, Sergei M., FALK, Karsten, PELIKAN, Juraj, BROWN, David A., TOMKOWICZ, Zbigniew, HAASE, Wolfgang. Orbital angular momentum contribution to the magneto-optical behavior of a binuclear cobalt(II) complex. In: Inorganic Chemistry, 2006, vol. 45, pp. 688-694. ISSN 0020-1669. DOI: https://doi.org/10.1021/ic0514748 |
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Inorganic Chemistry | |
Volumul 45 / 2006 / ISSN 0020-1669 | |
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DOI:https://doi.org/10.1021/ic0514748 | |
Pag. 688-694 | |
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We report magnetic and magnetic circular dichroism investigations of a binuclear Co(II) compound. The Hamiltonian of the system involves an isotropic exchange interaction dealing with the real spins of cobalt(II) ions, spin-orbit coupling, and a low-symmetry crystal field acting within the 4T 1g ground manifold of each cobalt ion. It is shown that spin-orbit coupling between this ground term and the low-lying excited ones can be taken into consideration as an effective g factor in the Zeeman part of the Hamiltonian. The value of this g factor is estimated for the averaged experimental values of Racah and cubic ligand field parameters for high-spin cobalt(II). The treatment of the Hamiltonian is performed with the use of a irreducible tensor operator technique. The results of the calculation are in good agreement with experimental observations. Both a large effective g factor for the ground state and a large temperature-independent part of the magnetic susceptibility arise because of a strong orbital contribution to the magnetic behavior of the Co(II) dimer. |
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