Conţinutul numărului revistei |
Articolul precedent |
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120 0 |
SM ISO690:2012 LARSEN, Finn Krebs, OVERGAARD, Jacob, PARSONS, Simon F., RENTSCHLER, Eva, SMITH, Andrew A., TIMKO, Grigore, WINPENNY, Richard E.P.. Horseshoes, Rings, and Distorted Rings: Studies of Cyclic Chromium-Fluoride Cages. In: Angewandte Chemie - International Edition, 2003, vol. 42, pp. 5978-5981. ISSN 1433-7851. DOI: https://doi.org/10.1002/anie.200352541 |
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Angewandte Chemie - International Edition | |
Volumul 42 / 2003 / ISSN 1433-7851 /ISSNe 1521-3773 | |
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DOI:https://doi.org/10.1002/anie.200352541 | |
Pag. 5978-5981 | |
Rezumat | |
Running rings around ammonium: Use of amine templates leads to a rich structural chemistry for heterometallic cyclic compounds. For example, use of two diethylammonium cations leads to the formation of the {Cr 10Cu2} cage, which is stabilized by N-H⋯F bonds (see picture). The results suggest a new method for making sophisticated polymetallic architectures. |
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Cuvinte-cheie Cage compounds, Chromium, heterometallic complexes, Supramolecular chemistry, template synthesis |
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