Structural phase transitions and stress accommodation in (formula presented) composite films
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LEBEDEV, Oleg, VERBEECK, Johann, VANTENDELOO, G, SHAPOVAL, Oleg M., BELENCHUK, Alexandr, MOSHNYAGA, Vasily T., DAMASCHKE, Bernd, SAMWER, Konrad H.. Structural phase transitions and stress accommodation in (formula presented) composite films. In: Physical Review B - Condensed Matter and Materials Physics, 2002, vol. 66, pp. 1-10. ISSN 1098-0121. DOI: https://doi.org/10.1103/PhysRevB.66.104421
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Physical Review B - Condensed Matter and Materials Physics
Volumul 66 / 2002 / ISSN 1098-0121 /ISSNe 1550-235X

Structural phase transitions and stress accommodation in (formula presented) composite films

DOI:https://doi.org/10.1103/PhysRevB.66.104421

Pag. 1-10

Lebedev Oleg1, Verbeeck Johann1, VanTendeloo G1, Shapoval Oleg M.2, Belenchuk Alexandr2, Moshnyaga Vasily T.3, Damaschke Bernd3, Samwer Konrad H.3
 
1 University of Antwerp,
2 Institute of Applied Physics, Academy of Sciences of Moldova,
3 I. Physikalisches Institut Uni-Goettingen
 
 
Disponibil în IBN: 7 iulie 2023


Rezumat

Composite (formula presented) films were prepared by metalorganic aerosol deposition on a (100)MgO substrate for different concentrations of the (MgO) phase (formula presented) At (formula presented) a percolation threshold in conductivity is reached, at which an infinite insulating MgO cluster forms around the (formula presented) grains. This yields a drastic increase of the electrical resistance for films with (formula presented) The film structure is characterized by x-ray diffraction and transmission electron microscopy. The local structure of the (formula presented) within the film depends on the MgO concentration which grows epitaxially along the domain boundaries. A different structural phase transition from the orthorhombic Pnma structure to an unusual rhombohedral (formula presented) structure at the percolation threshold (formula presented) is found for (formula presented) A three-dimensional stress accommodation in thick films through a phase transition is suggested. 

Cuvinte-cheie
perovskite, Magnetoresistance, Galvanomagnetic Effects